About: Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of gamma-Fe2O3 nanoparticles     Goto   Sponge   NotDistinct   Permalink

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  • The effect of a hydrophobic (oleic acid) coating on the magnetic properties of maghemite (gamma-Fe2O3) nanoparticles was investigated. The nanoparticles were prepared by a novel bi-phasic co-precipitation route and their properties compared with uncoated nanoparticles and nanoparticles prepared by a standard single-phase process. The oleic acid coated nanoparticles had a mean diameter of 6 nm when the two-phase precipitation procedure was used compared to 12 nm for nanoparticles prepared in a single phase under otherwise identical conditions. Super Quantum Interference Device measurements show superparamagnetism of the nanoparticles, with a saturation magnetization at 4 K to be 66.4 emu/g and 89.0 emu/g for the coated nanoparticles obtained by two- and single-phase procedure, respectively. Zero-field-cooled and field-cooled curves reveal a dramatic shift in the blocking temperature of the coated nanoparticles, and a significant change in their anisotropy. The hydrophobic nanoparticles were able to form stable ferrofluids in a range of organic solvents and show good heating rates in a 400 kHz alternating magnetic field.
  • The effect of a hydrophobic (oleic acid) coating on the magnetic properties of maghemite (gamma-Fe2O3) nanoparticles was investigated. The nanoparticles were prepared by a novel bi-phasic co-precipitation route and their properties compared with uncoated nanoparticles and nanoparticles prepared by a standard single-phase process. The oleic acid coated nanoparticles had a mean diameter of 6 nm when the two-phase precipitation procedure was used compared to 12 nm for nanoparticles prepared in a single phase under otherwise identical conditions. Super Quantum Interference Device measurements show superparamagnetism of the nanoparticles, with a saturation magnetization at 4 K to be 66.4 emu/g and 89.0 emu/g for the coated nanoparticles obtained by two- and single-phase procedure, respectively. Zero-field-cooled and field-cooled curves reveal a dramatic shift in the blocking temperature of the coated nanoparticles, and a significant change in their anisotropy. The hydrophobic nanoparticles were able to form stable ferrofluids in a range of organic solvents and show good heating rates in a 400 kHz alternating magnetic field. (en)
Title
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of gamma-Fe2O3 nanoparticles
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of gamma-Fe2O3 nanoparticles (en)
skos:prefLabel
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of gamma-Fe2O3 nanoparticles
  • Effect of hydrophobic coating on the magnetic anisotropy and radiofrequency heating of gamma-Fe2O3 nanoparticles (en)
skos:notation
  • RIV/00216208:11320/13:10139980!RIV14-GA0-11320___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP108/10/1006), P(GPP206/11/P405), P(LM2011025)
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  • August
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  • 71552
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  • RIV/00216208:11320/13:10139980
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  • Maghemite; Blocking temperature; Saturation magnetization; Superparamagnetism; Nanoparticle (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
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  • [880AE100D932]
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  • Journal of Magnetism and Magnetic Materials
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  • 339
http://linked.open...iv/tvurceVysledku
  • Svoboda, Pavel
  • Šantavá, Eva
  • Štěpánek, František
  • Prokopec, Vadym
  • Singh, Mandeep
  • Ulbrich, Pavel
http://linked.open...ain/vavai/riv/wos
  • 000318904100019
issn
  • 0304-8853
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jmmm.2013.02.051
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  • 11320
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