About: Two-dimensional correlation analysis of Raman optical activity

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Two-dimensional correlation analysis of Raman optical activity - Basic rules and data treatment Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.sciencedirect.com/science/article/pii/S092420311100138X
Description	Here we present the comparison of simulations of wavenumber, intensity and bandwidth changes in VOA couplets and of classical bands analyzed by 2DCoS. This showed that Noda's rules are directly applicable to asynchronous part of 2DCoS but must be reversed for the synchronous part of 2DCoS. Thus, some of the spectral changes exhibit similar 2DCoS patterns which can be deduced from single band analogies. Nevertheless, other analogies may be misguided because several spectral events in VOA show similar patterns as very distant cases in classical bands. We also developed new data treatment of ROA spectral series based on principal component analysis (PCA). The core of the treatment lies in baseline corrections in PCA subspectra and subsequent usage of significant corrected subspectra for ROA data reconstruction. This removes spectral noise, background variations as well as unwanted distortions of the ROA baseline. Here we present the comparison of simulations of wavenumber, intensity and bandwidth changes in VOA couplets and of classical bands analyzed by 2DCoS. This showed that Noda's rules are directly applicable to asynchronous part of 2DCoS but must be reversed for the synchronous part of 2DCoS. Thus, some of the spectral changes exhibit similar 2DCoS patterns which can be deduced from single band analogies. Nevertheless, other analogies may be misguided because several spectral events in VOA show similar patterns as very distant cases in classical bands. We also developed new data treatment of ROA spectral series based on principal component analysis (PCA). The core of the treatment lies in baseline corrections in PCA subspectra and subsequent usage of significant corrected subspectra for ROA data reconstruction. This removes spectral noise, background variations as well as unwanted distortions of the ROA baseline. (en)
Title	Two-dimensional correlation analysis of Raman optical activity - Basic rules and data treatment Two-dimensional correlation analysis of Raman optical activity - Basic rules and data treatment (en)
skos:prefLabel	Two-dimensional correlation analysis of Raman optical activity - Basic rules and data treatment Two-dimensional correlation analysis of Raman optical activity - Basic rules and data treatment (en)
skos:notation	RIV/00216208:11320/12:10099149!RIV13-GA0-11320___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GAP205/10/1276), P(GP202/06/P208), Z(MSM0021620835)
http://linked.open...iv/cisloPeriodika	May
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Pazderka, Tomáš Kopecký, Vladimír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Matematicko-fyzikální fakulta
http://linked.open...dnocenehoVysledku	175490
http://linked.open...ai/riv/idVysledku	RIV/00216208:11320/12:10099149
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	data treatment; Noda's rules; principal component analysis; two-dimensional correlation spectroscopy; vibrational optical activity; Raman optical activity (en)
http://linked.open.../riv/klicoveSlovo	Noda's rules data treatment two-dimensional correlation spectroscopy principal component analysis Raman optical activity vibrational optical activity
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[8E3022F73D34]
http://linked.open...i/riv/nazevZdroje	Vibrational Spectroscopy
http://linked.open...in/vavai/riv/obor	BO
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Structural and binding properties of human alpha(1)-acid glycoprotein Interactions of disulfide groups in peptide/ protein molecules - complementary use of electronic and vibrational optical activity
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	60
http://linked.open...iv/tvurceVysledku	Kopecký, Vladimír Pazderka, Tomáš
http://linked.open...ain/vavai/riv/wos	000304685700036
http://linked.open...n/vavai/riv/zamer	Fyzika molekulárních, makromolekulárních a biologických systémů
issn	0924-2031
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.vibspec.2011.10.002
http://localhost/t...ganizacniJednotka	11320

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software