About: Direct C-H amination and C-H chloroamination of 7-deazapurines     Goto   Sponge   NotDistinct   Permalink

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Description
  • Protocols for selective Pd-Cu-catalyzed direct C-H amination or C-H chloroamination of 7-deazapurines with N-chloro-N-alkyl-arylsulfonamides have been developed leading either to 8-(arylsulfonyl)methylamino-7-deazapurines or to 7-chloro-8-(arylsulfonyl)methylamino-7-deazapurines. The scope and limitations of the methods, as well as synthesis of a small series of 6,8,9-tri- and 6,7,8,9-tetrasubstituted 7-deazapurines and deprotection of the sulfonamide are presented.
  • Protocols for selective Pd-Cu-catalyzed direct C-H amination or C-H chloroamination of 7-deazapurines with N-chloro-N-alkyl-arylsulfonamides have been developed leading either to 8-(arylsulfonyl)methylamino-7-deazapurines or to 7-chloro-8-(arylsulfonyl)methylamino-7-deazapurines. The scope and limitations of the methods, as well as synthesis of a small series of 6,8,9-tri- and 6,7,8,9-tetrasubstituted 7-deazapurines and deprotection of the sulfonamide are presented. (en)
Title
  • Direct C-H amination and C-H chloroamination of 7-deazapurines
  • Direct C-H amination and C-H chloroamination of 7-deazapurines (en)
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  • Direct C-H amination and C-H chloroamination of 7-deazapurines
  • Direct C-H amination and C-H chloroamination of 7-deazapurines (en)
skos:notation
  • RIV/00216208:11310/14:10286001!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/12/0205)
http://linked.open...iv/cisloPeriodika
  • 107
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 11635
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/14:10286001
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  • 7-deazapurines; cross-coupling reactions; catalyzed direct amination (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [90F129786EF8]
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  • 4
http://linked.open...iv/tvurceVysledku
  • Hocek, Michal
  • Klepetářová, Blanka
  • Klečka, Martin
  • Sabat, Nazarii
  • Slavětinská, Lenka
http://linked.open...ain/vavai/riv/wos
  • 000345660300015
issn
  • 2046-2069
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c4ra13143f
http://localhost/t...ganizacniJednotka
  • 11310
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