About: Modular Synthesis of Helicene-Like Compounds Based on the Imidazolium Motif

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1002/ejoc.201402746
Description	Straightforward synthesis of novel mono-and tricationic helical compounds based on the imidazolium core has been developed. The synthetic route based on double [2+2+2] cyclo-addition reactions of precursors with the imidazolium core motif is notably modular and reaches beyond established protocols used for the synthesis of imidazolium systems as well as beyond the reported protocols used to assemble compounds with helical frameworks. This approach opens rapid four-step access to a cationic species featuring nine ortho-annulated rings that represents the highest order helical nitrogen-based cationic system reported to date. Straightforward synthesis of novel mono-and tricationic helical compounds based on the imidazolium core has been developed. The synthetic route based on double [2+2+2] cyclo-addition reactions of precursors with the imidazolium core motif is notably modular and reaches beyond established protocols used for the synthesis of imidazolium systems as well as beyond the reported protocols used to assemble compounds with helical frameworks. This approach opens rapid four-step access to a cationic species featuring nine ortho-annulated rings that represents the highest order helical nitrogen-based cationic system reported to date. (en)
Title	Modular Synthesis of Helicene-Like Compounds Based on the Imidazolium Motif Modular Synthesis of Helicene-Like Compounds Based on the Imidazolium Motif (en)
skos:prefLabel	Modular Synthesis of Helicene-Like Compounds Based on the Imidazolium Motif Modular Synthesis of Helicene-Like Compounds Based on the Imidazolium Motif (en)
skos:notation	RIV/00216208:11310/14:10277917!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(GA13-19213S), P(GA13-32974S), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	26
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Císařová, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	30203
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/14:10277917
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electrophoresis; [2+2+2] cycloaddition; helical structures; nitrogen heterocycles; synthetic methods (en)
http://linked.open.../riv/klicoveSlovo	electrophoresis nitrogen heterocycles synthetic methods [2+2+2] cycloaddition helical structures
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[99779329A27D]
http://linked.open...i/riv/nazevZdroje	European Journal of Organic Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Syntéza helikálních cyaninů, jejich chiralita, samouspořádání a redoxní přepínání Enantioseparace významných analytů: Helikální dikationty jako nové chirální selektory
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	neuveden
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Kašička, Václav Koval, Dušan Teplý, Filip Šaman, David Klepetářová, Blanka Čížková, Martina
http://linked.open...ain/vavai/riv/wos	000341769700007
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1434-193X
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/ejoc.201402746
http://localhost/t...ganizacniJednotka	11310

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