About: Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
rdfs:seeAlso
Description
  • Reductive elimination of ethane from the palladium(IV) complex [PdMe3(bpy)I] (bpy = 2,2'-bipyridine) is studied by electrospray ionization mass spectrometry. Palladium(IV) complexes can be detected as binuclear clusters [Pd2Me6I(bpy)(2)](+) or as complexes [PdMe3(bpy)(L)](+) stabilized by an electron-donating ligand L. Fragmentation of all palladium(W) complexes is dominated by elimination of ethane which corresponds to the reductive elimination coupling of the methyl groups. The associated energy demands for different complexes reveal that the mononuclear complexes with poorly electron-donating ligands provide the fastest reaction.
  • Reductive elimination of ethane from the palladium(IV) complex [PdMe3(bpy)I] (bpy = 2,2'-bipyridine) is studied by electrospray ionization mass spectrometry. Palladium(IV) complexes can be detected as binuclear clusters [Pd2Me6I(bpy)(2)](+) or as complexes [PdMe3(bpy)(L)](+) stabilized by an electron-donating ligand L. Fragmentation of all palladium(W) complexes is dominated by elimination of ethane which corresponds to the reductive elimination coupling of the methyl groups. The associated energy demands for different complexes reveal that the mononuclear complexes with poorly electron-donating ligands provide the fastest reaction. (en)
Title
  • Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes
  • Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes (en)
skos:prefLabel
  • Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes
  • Mass Spectrometric Studies of Reductive Elimination from Pd(IV) Complexes (en)
skos:notation
  • RIV/00216208:11310/14:10209528!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/11/0338)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 27511
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/14:10209528
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • product; reagents; catalysis; chemistry; intermediate; mechanism; reactivity; palladium(IV); oxidative addition; cross-coupling reactions (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [4DAE3F4454EC]
http://linked.open...i/riv/nazevZdroje
  • Organic Letters
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 16
http://linked.open...iv/tvurceVysledku
  • Roithová, Jana
  • Hývl, Jakub
http://linked.open...ain/vavai/riv/wos
  • 000329472800052
issn
  • 1523-7060
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/ol403190g
http://localhost/t...ganizacniJednotka
  • 11310
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 67 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software