About: Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices     Goto   Sponge   NotDistinct   Permalink

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Description
  • Controllable fabrication of highly porous iron vanadate (FeVO4) thick film consisting of disordered nanorods suitable for gas penetration and permeation was achieved by hydrothermal synthesis of fervanite-like FeVO4 center dot 1.1H2O. The subsequent dehydration to FeVO4 was investigated by Fe-57 Mossbauer spectroscopy (DQS), DTA, magnetic susceptibility (c) and electron microscopy (REM/TEM). Their integration in gas sensing devices as porous layer via polymer-blended (PVDF) doctor-blading approach was successfully demonstrated followed by investigations of their electric properties and oxygen sensing capability. The probed I-U behaviour and UV-Vis measurements confirmed the semiconducting nature of triclinic FeVO4 (E-g = 2.72 eV) and exhibited an activation energy for electric conduction of 0.46 eV. The best sensitivity of 0.29 +/- 0.01 (m = -3.4 +/- 0.1) could be obtained at an optimal working temperature of 250 degrees C.
  • Controllable fabrication of highly porous iron vanadate (FeVO4) thick film consisting of disordered nanorods suitable for gas penetration and permeation was achieved by hydrothermal synthesis of fervanite-like FeVO4 center dot 1.1H2O. The subsequent dehydration to FeVO4 was investigated by Fe-57 Mossbauer spectroscopy (DQS), DTA, magnetic susceptibility (c) and electron microscopy (REM/TEM). Their integration in gas sensing devices as porous layer via polymer-blended (PVDF) doctor-blading approach was successfully demonstrated followed by investigations of their electric properties and oxygen sensing capability. The probed I-U behaviour and UV-Vis measurements confirmed the semiconducting nature of triclinic FeVO4 (E-g = 2.72 eV) and exhibited an activation energy for electric conduction of 0.46 eV. The best sensitivity of 0.29 +/- 0.01 (m = -3.4 +/- 0.1) could be obtained at an optimal working temperature of 250 degrees C. (en)
Title
  • Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices
  • Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices (en)
skos:prefLabel
  • Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices
  • Hydrothermally grown porous FeVO4 nanorods and their integration as active material in gas-sensing devices (en)
skos:notation
  • RIV/00216208:11310/14:10194154!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 20131
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  • RIV/00216208:11310/14:10194154
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  • sensitivity; degradation; nanocrystals; form; orthovanadate; pressure; thin-films; metal-oxides; electrochemical properties; temperature oxygen sensors (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B96EDEB878A9]
http://linked.open...i/riv/nazevZdroje
  • Journal of Materials Chemistry A
http://linked.open...in/vavai/riv/obor
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  • 2
http://linked.open...iv/tvurceVysledku
  • Nižňanský, Daniel
  • Mathur, Sanjay
  • Valldor, Martin
  • Lehnen, Thomas
http://linked.open...ain/vavai/riv/wos
  • 000329935700035
issn
  • 2050-7488
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c3ta12821k
http://localhost/t...ganizacniJednotka
  • 11310
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