About: Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1039/C3CE42306A
Description	Eight inorganic salts of 2-amino-1,3,4-thiadiazole (2-athd) with hydrochloric, perchloric, nitric, sulphuric, selenic, phosphorous and phosphoric acids were prepared, and their crystal structures were determined. Seven of the compounds crystallise in monoclinic space groups - i.e., 2-athd(1+) chloride monohydrate (P21/c), 2-athd(1+) selenate monohydrate (Pc), 2- athd(1+) dihydrogen phosphate (Cc), 2-athd(1+) phosphite (P21/a), 2-athd(1+) nitrate (P21/c), 2-athd(1+) 2-athd perchlorate (P21/n) and 2-athd(1+) perchlorate (P21/c) - and one crystallises in an orthorhombic space group - 2-athd(1+) hydrogen sulphate (P212121). The thermal behaviours of the materials were studied (DSC) down to liquid nitrogen temperature, and the properties of the perchlorates, hydrogen sulphate and selenate monohydrate crystals were discussed with respect to the results of high or low-temperature X-ray diffraction, IR and Raman spectroscopic study. Quantitative measurements of the second harmonic generation of the powdered non-centrosymmetric samples at 1064 and 800 nm were performed and a relative efficiency compared to KDP is presented. Eight inorganic salts of 2-amino-1,3,4-thiadiazole (2-athd) with hydrochloric, perchloric, nitric, sulphuric, selenic, phosphorous and phosphoric acids were prepared, and their crystal structures were determined. Seven of the compounds crystallise in monoclinic space groups - i.e., 2-athd(1+) chloride monohydrate (P21/c), 2-athd(1+) selenate monohydrate (Pc), 2- athd(1+) dihydrogen phosphate (Cc), 2-athd(1+) phosphite (P21/a), 2-athd(1+) nitrate (P21/c), 2-athd(1+) 2-athd perchlorate (P21/n) and 2-athd(1+) perchlorate (P21/c) - and one crystallises in an orthorhombic space group - 2-athd(1+) hydrogen sulphate (P212121). The thermal behaviours of the materials were studied (DSC) down to liquid nitrogen temperature, and the properties of the perchlorates, hydrogen sulphate and selenate monohydrate crystals were discussed with respect to the results of high or low-temperature X-ray diffraction, IR and Raman spectroscopic study. Quantitative measurements of the second harmonic generation of the powdered non-centrosymmetric samples at 1064 and 800 nm were performed and a relative efficiency compared to KDP is presented. (en)
Title	Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties (en)
skos:prefLabel	Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties Molecular Crystals of 2-amino-1,3,4-thiadiazole with Inorganic Oxyacids - Crystal Engineering, Phase Transformations and NLO Properties (en)
skos:notation	RIV/00216208:11310/14:10159367!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita	I S Z
http://linked.open...avai/riv/aktivity	I, S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Matulková, Irena Cihelka, Jaroslav Němec, Ivan Císařová, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	30277
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/14:10159367
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	phase transformations; second harmonic generation; vibrational spectroscopy; crystal structure; 2-amino-1,3,4-thiadiazole (en)
http://linked.open.../riv/klicoveSlovo	2-amino-1 4-thiadiazole phase transformations crystal structure vibrational spectroscopy 3 second harmonic generation
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[C825F7C44B49]
http://linked.open...i/riv/nazevZdroje	CrystEngComm
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	11 (xsd:int)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	16
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Dušek, Michal Fejfarová, Karla Matulková, Irena Němec, Ivan Němec, Petr Cihelka, Jaroslav Vaněk, Přemysl Kroupa, Jan Tesařová, Naďa Pojarová, Michalea
http://linked.open...ain/vavai/riv/wos	000331175900022
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1466-8033
number of pages	14 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/C3CE42306A
http://localhost/t...ganizacniJednotka	11310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software