About: Micellization of Zonyl FSN-100 Fluorosurfactant in Aqueous Solutions     Goto   Sponge   NotDistinct   Permalink

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Description
  • We report on micellization of nonionic fluorosurfactant Zonyl FSN-100 in aqueous solutions studiedby means of NMR spectroscopy, light and small-angle X-ray scattering, surface tension measurements,isothermal titration calorimetry and fluorescence spectroscopy. The results allow for determination ofbasic parameters of Zonyl FSN-100 association like critical micellar concentration, size and associationnumber of Zonyl FSN-100 micelles which have a core-shell structure with the core of fluorocarbon chainsand the shell of oligo(ethylene oxide) chains. Time-resolved fluorescence spectroscopy studies using1,6-diphenyl-1,3,5-hexatriene (DPH) as a fluorescent probe indicate that DPH can be solubilized in themicelles despite the general assumption about the immiscibility of hydrocarbon compounds with thefluorocarbon core of the micelles.
  • We report on micellization of nonionic fluorosurfactant Zonyl FSN-100 in aqueous solutions studiedby means of NMR spectroscopy, light and small-angle X-ray scattering, surface tension measurements,isothermal titration calorimetry and fluorescence spectroscopy. The results allow for determination ofbasic parameters of Zonyl FSN-100 association like critical micellar concentration, size and associationnumber of Zonyl FSN-100 micelles which have a core-shell structure with the core of fluorocarbon chainsand the shell of oligo(ethylene oxide) chains. Time-resolved fluorescence spectroscopy studies using1,6-diphenyl-1,3,5-hexatriene (DPH) as a fluorescent probe indicate that DPH can be solubilized in themicelles despite the general assumption about the immiscibility of hydrocarbon compounds with thefluorocarbon core of the micelles. (en)
Title
  • Micellization of Zonyl FSN-100 Fluorosurfactant in Aqueous Solutions
  • Micellization of Zonyl FSN-100 Fluorosurfactant in Aqueous Solutions (en)
skos:prefLabel
  • Micellization of Zonyl FSN-100 Fluorosurfactant in Aqueous Solutions
  • Micellization of Zonyl FSN-100 Fluorosurfactant in Aqueous Solutions (en)
skos:notation
  • RIV/00216208:11310/14:10145629!RIV15-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(7AMB13PL026), P(GAP106/12/0143), P(GPP208/12/P236), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 20 February 2014
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 29127
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/14:10145629
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • micelles; fluorescence; scattering; fluorosurfactant (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [63FD33A7D120]
http://linked.open...i/riv/nazevZdroje
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 443
http://linked.open...iv/tvurceVysledku
  • Procházka, Karel
  • Uchman, Mariusz Marcin
  • Štěpánek, Miroslav
  • Tošner, Zdeněk
  • Pispas, Stergios
  • Škvarla, Juraj
  • Garamus, Vasil
http://linked.open...ain/vavai/riv/wos
  • 000342501300030
http://linked.open...n/vavai/riv/zamer
issn
  • 0927-7757
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.colsurfa.2013.11.021
http://localhost/t...ganizacniJednotka
  • 11310
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