About: Practical Aspects of Complexation of Buffer Constituents with Neutral Complexation Agents in Capillary Electrophoresis

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://www.chemicke-listy.cz/docs/full/2013_s3_s312-s342.pdf
Description	The complexation of buffer constituents with the complexation agent present in the solution can very significantly influence the buffer properties, such as pH, ionic strength or conductivity. These parameters are often crucial for selection of the optimal separation conditions in analytical separation techniques, particularly for capillary electrophoresis. We demonstrate that even commonly used buffers significnatly complex with usual chiral selectors as neutral cyclodextrins. This type of complexation and the subsequent change in properties of the buffer can have subsequent practical aspects in capillary electrophoresis; namely on determination of complexation constants, development of system peaks and last but not least can deterioritate the results of electrophoretic separation. The complexation of buffer constituents with the complexation agent present in the solution can very significantly influence the buffer properties, such as pH, ionic strength or conductivity. These parameters are often crucial for selection of the optimal separation conditions in analytical separation techniques, particularly for capillary electrophoresis. We demonstrate that even commonly used buffers significnatly complex with usual chiral selectors as neutral cyclodextrins. This type of complexation and the subsequent change in properties of the buffer can have subsequent practical aspects in capillary electrophoresis; namely on determination of complexation constants, development of system peaks and last but not least can deterioritate the results of electrophoretic separation. (en)
Title	Practical Aspects of Complexation of Buffer Constituents with Neutral Complexation Agents in Capillary Electrophoresis Practical Aspects of Complexation of Buffer Constituents with Neutral Complexation Agents in Capillary Electrophoresis (en)
skos:prefLabel	Practical Aspects of Complexation of Buffer Constituents with Neutral Complexation Agents in Capillary Electrophoresis Practical Aspects of Complexation of Buffer Constituents with Neutral Complexation Agents in Capillary Electrophoresis (en)
skos:notation	RIV/00216208:11310/13:10189791!RIV14-GA0-11310___
http://linked.open...avai/riv/aktivita	I P S Z
http://linked.open...avai/riv/aktivity	I, P(GPP206/12/P630), P(LH11018), S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	SI, Suplement 3
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Gaš, Bohuslav Svobodová, Jana Tesařová, Eva Beneš, Martin Riesová, Martina
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	98195
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/13:10189791
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cyclodextrins; simulation; formation equilibria (en)
http://linked.open.../riv/klicoveSlovo	formation equilibria simulation cyclodextrins
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[8FAD17D7DB19]
http://linked.open...i/riv/nazevZdroje	Chemické listy
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Unified model and integrated computational tools for (dynamic) chiral separation in capillary zone electrophoresis Cyclofructans and their derivatives as new chiral selectors for liquid chromatography and capillary electrophoresis
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	107
http://linked.open...iv/tvurceVysledku	Gaš, Bohuslav Svobodová, Jana Tesařová, Eva Beneš, Martin Riesová, Martina
http://linked.open...ain/vavai/riv/wos	000328730800018
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0009-2770
number of pages	2 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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