About: Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds     Goto   Sponge   NotDistinct   Permalink

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Description
  • The highly enantioselective organocatalytic alpha-selenylation reaction of aldehydes using a hypervalent iodine compound as an oxidative agent from commercially available phenyl diselenide under mild oxidative conditions is described. This transformation affords alpha-selenyl aldehydes in good yields and with excellent enantioselectivities. By using hypervalent iodine compounds, it opens up a suitable and alternative way for the preparation of biologically active building blocks such as beta-hydroxy alcohols, alpha-amino acids, and alpha-hydroxy esters.
  • The highly enantioselective organocatalytic alpha-selenylation reaction of aldehydes using a hypervalent iodine compound as an oxidative agent from commercially available phenyl diselenide under mild oxidative conditions is described. This transformation affords alpha-selenyl aldehydes in good yields and with excellent enantioselectivities. By using hypervalent iodine compounds, it opens up a suitable and alternative way for the preparation of biologically active building blocks such as beta-hydroxy alcohols, alpha-amino acids, and alpha-hydroxy esters. (en)
Title
  • Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds
  • Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds (en)
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  • Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds
  • Highly enantioselective organocatalytic alpha-selenylation of aldehydes using hypervalent iodine compounds (en)
skos:notation
  • RIV/00216208:11310/13:10159270!RIV14-GA0-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/10/0428), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 5-6
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 77403
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/13:10159270
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • esters; selenenylation; organic-synthesis; selenium reagents; glutathione-peroxidase; organoselenium chemistry; alpha,beta-unsaturated aldehydes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [EF95D5FD7DCA]
http://linked.open...i/riv/nazevZdroje
  • Tetrahedron Asymmetry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 24
http://linked.open...iv/tvurceVysledku
  • Veselý, Jan
  • Kamlar, Martin
http://linked.open...ain/vavai/riv/wos
  • 000316843000003
http://linked.open...n/vavai/riv/zamer
issn
  • 0957-4166
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tetasy.2013.02.008
http://localhost/t...ganizacniJednotka
  • 11310
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