About: Microbial effects on the release and attenuation of arsenic in the shallow subsurface of a natural geochemical anomaly     Goto   Sponge   NotDistinct   Permalink

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Description
  • Critical factors leading to arsenic release and attenuation from the shallow subsurface were studied with multidisciplinary approach in the natural gold-arsenic geochemical anomaly at Mokrsko (Czech Republic). The results show that microbial reduction promotes arsenic release from Fe(III) (hydr)oxides and Fe(III) arsenates, thereby enhancing dissolved arsenic in the shallow groundwater at average concentration of 7.76 mg/L. In the organic-rich aggregates and wood particles, however, microbial sulfate reduction triggers the formation of realgar deposits, leading to accumulation of As in the distinct organic-rich patches of the shallow subsurface. We conclude that precipitation of realgar in the shallow subsurface of soil/sediment depends on specific and non-trivial combination of water and rock chemistry, microbial community composition and spatial organisation of the subsurface zone, where speciation in saturated environments varied on a centimeter scale from reduced (decomposed wood, H2S and realgar present) to oxidized (goethite and arsenate minerals are present).
  • Critical factors leading to arsenic release and attenuation from the shallow subsurface were studied with multidisciplinary approach in the natural gold-arsenic geochemical anomaly at Mokrsko (Czech Republic). The results show that microbial reduction promotes arsenic release from Fe(III) (hydr)oxides and Fe(III) arsenates, thereby enhancing dissolved arsenic in the shallow groundwater at average concentration of 7.76 mg/L. In the organic-rich aggregates and wood particles, however, microbial sulfate reduction triggers the formation of realgar deposits, leading to accumulation of As in the distinct organic-rich patches of the shallow subsurface. We conclude that precipitation of realgar in the shallow subsurface of soil/sediment depends on specific and non-trivial combination of water and rock chemistry, microbial community composition and spatial organisation of the subsurface zone, where speciation in saturated environments varied on a centimeter scale from reduced (decomposed wood, H2S and realgar present) to oxidized (goethite and arsenate minerals are present). (en)
Title
  • Microbial effects on the release and attenuation of arsenic in the shallow subsurface of a natural geochemical anomaly
  • Microbial effects on the release and attenuation of arsenic in the shallow subsurface of a natural geochemical anomaly (en)
skos:prefLabel
  • Microbial effects on the release and attenuation of arsenic in the shallow subsurface of a natural geochemical anomaly
  • Microbial effects on the release and attenuation of arsenic in the shallow subsurface of a natural geochemical anomaly (en)
skos:notation
  • RIV/00216208:11310/13:10139383!RIV14-GA0-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GPP210/10/P096), S, Z(AV0Z30130516), Z(MSM0021620855), Z(MSM0021620858)
http://linked.open...iv/cisloPeriodika
  • neuvedeno
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 88148
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/13:10139383
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Realgar; dsrB; arrA; Microbial mobilization; Arsenic (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [46B393D71925]
http://linked.open...i/riv/nazevZdroje
  • Environmental Pollution
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 180
http://linked.open...iv/tvurceVysledku
  • Matoušek, Tomáš
  • Rohovec, Jan
  • Drahota, Petr
  • Čepička, Ivan
  • Falteisek, Lukáš
  • Redlich, Aleš
http://linked.open...ain/vavai/riv/wos
  • 000322425300013
http://linked.open...n/vavai/riv/zamer
issn
  • 0269-7491
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.envpol.2013.05.010
http://localhost/t...ganizacniJednotka
  • 11310
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