About: A family of zeolites with controlled pore size prepared using a top-down method

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The properties of zeolites, and thus their suitability for different applications, are intimately connected with their structures. Synthesizing specific architectures is therefore important, but has remained challenging. Here we report a topdown strategy that involves the disassembly of a parent zeolite, UTL, and its reassembly into two zeolites with targeted topologies, IPC-2 and IPC-4. The three zeolites are closely related as they adopt the same layered structure, and they differ only in how the layers are connected. Choosing different linkers gives rise to different pore sizes, enabling the synthesis of materials with predetermined pore architectures. The structures of the resulting zeolites were characterized by interpreting the X-ray powder-diffraction patterns through models using computational methods; IPC-2 exhibits orthogonal 12- and ten-ring channels, and IPC-4 is a more complex zeolite that comprises orthogonal ten- and eight-ring channels. We describe how this method enables the preparation of functional materials and discuss its potential for targeting other new zeolites. The properties of zeolites, and thus their suitability for different applications, are intimately connected with their structures. Synthesizing specific architectures is therefore important, but has remained challenging. Here we report a topdown strategy that involves the disassembly of a parent zeolite, UTL, and its reassembly into two zeolites with targeted topologies, IPC-2 and IPC-4. The three zeolites are closely related as they adopt the same layered structure, and they differ only in how the layers are connected. Choosing different linkers gives rise to different pore sizes, enabling the synthesis of materials with predetermined pore architectures. The structures of the resulting zeolites were characterized by interpreting the X-ray powder-diffraction patterns through models using computational methods; IPC-2 exhibits orthogonal 12- and ten-ring channels, and IPC-4 is a more complex zeolite that comprises orthogonal ten- and eight-ring channels. We describe how this method enables the preparation of functional materials and discuss its potential for targeting other new zeolites. (en)
Title	A family of zeolites with controlled pore size prepared using a top-down method A family of zeolites with controlled pore size prepared using a top-down method (en)
skos:prefLabel	A family of zeolites with controlled pore size prepared using a top-down method A family of zeolites with controlled pore size prepared using a top-down method (en)
skos:notation	RIV/00216208:11310/13:10134295!RIV14-GA0-11310___
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GBP106/12/G015)
http://linked.open...iv/cisloPeriodika	7
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Položij, Miroslav Nachtigall, Petr Grajciar, Lukáš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	58603
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/13:10134295
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	nuclear magnetic resonance spectroscopy; chemical structure; zeolites (en)
http://linked.open.../riv/klicoveSlovo	nuclear magnetic resonance spectroscopy chemical structure zeolites
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[27FFEE3CDB5A]
http://linked.open...i/riv/nazevZdroje	Nature Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	12 (xsd:int)
http://linked.open...vavai/riv/projekt	Intelligent design of nanoporous adsorbents and catalysts
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	5
http://linked.open...iv/tvurceVysledku	Grajciar, Lukáš Nachtigall, Petr Zukal, Arnošt Čejka, Jiří Chlubná, Pavla Roth, W. J. Ashbrook, S. E. Morris, R. E. Položij, Miroslav Seymour, V. Shvets, Oleksiy Wheatley, P. S.
http://linked.open...ain/vavai/riv/wos	000321042600017
issn	1755-4330
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1038/NCHEM.1662
http://localhost/t...ganizacniJednotka	11310

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