About: Effect of cations on polyaniline morphology

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.2478/s11696-013-0352-6
Description	Nanostructured polyanilines of different morphologies were prepared by chemical polymerization of aniline with ammonium peroxodisulfate in aqueous HCl using various inorganic and organic chlorides as additives with the aim to determine the effect of cations of the added electrolyte on the morphology, spectroscopic characteristics, and conductivity of formed polyanilines. Chlorides of basic metals: NaCl and CaCl2 did not show any significant effect while AlCl3 and organic electrolytes were found to influence the morphology of polyanilines. The effect of organic-electrolyte additives, which actually are ionic liquids, is explained by the organization of their molecules to micellar structures that act as soft templates for emerging polyaniline nanoparticles. The effect of AlCl3 is ascribed to the transformation of its molecules to [AlCl4]MINUS SIGN anions. Nanostructured polyanilines of different morphologies were prepared by chemical polymerization of aniline with ammonium peroxodisulfate in aqueous HCl using various inorganic and organic chlorides as additives with the aim to determine the effect of cations of the added electrolyte on the morphology, spectroscopic characteristics, and conductivity of formed polyanilines. Chlorides of basic metals: NaCl and CaCl2 did not show any significant effect while AlCl3 and organic electrolytes were found to influence the morphology of polyanilines. The effect of organic-electrolyte additives, which actually are ionic liquids, is explained by the organization of their molecules to micellar structures that act as soft templates for emerging polyaniline nanoparticles. The effect of AlCl3 is ascribed to the transformation of its molecules to [AlCl4]MINUS SIGN anions. (en)
Title	Effect of cations on polyaniline morphology Effect of cations on polyaniline morphology (en)
skos:prefLabel	Effect of cations on polyaniline morphology Effect of cations on polyaniline morphology (en)
skos:notation	RIV/00216208:11310/13:10134198!RIV14-GA0-11310___
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(GA104/09/1435), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Vohlídal, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	71398
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/13:10134198
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electrolytes; morphology; ionic liquids; nanostructures; polyaniline (en)
http://linked.open.../riv/klicoveSlovo	ionic liquids electrolytes morphology nanostructures polyaniline
http://linked.open...odStatuVydavatele	SK - Slovenská republika
http://linked.open...ontrolniKodProRIV	[4218321A9DBE]
http://linked.open...i/riv/nazevZdroje	Chemical Papers
http://linked.open...in/vavai/riv/obor	CD
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Advanced catalytic processes for preparation of organic photoelectronic materials
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	67
http://linked.open...iv/tvurceVysledku	Pahovnik, David Vohlídal, Jiří Žigon, Majda Žagar, Ema
http://linked.open...ain/vavai/riv/wos	000318443700012
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0366-6352
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.2478/s11696-013-0352-6
http://localhost/t...ganizacniJednotka	11310

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