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  • In this study the possibility to detect biomarkers in experimentally prepared evaporitic matrices using a portable Raman instrument was estimated. Testing of the instrument was carried-out under the Alpine conditions outdoors at a low ambient temperature of -10 degrees C and at an altitude of 2860 m (Pitztal, Austria). Amino acids glycine and L-alanine, nucleo bases thymine and adenine, and metabolite urea were the organics mixed with gypsum powder. In this step it was shown that portable Raman spectroscopic instrumentation is capable of detecting biomarkers in complex samples in a host geological matrix. Such detection is possible even when the laser beam was focussed through the gypsum crystals 3-9 mm thick. For exobiology areas, this is an important fact, because life and/or related biomolecules are likely to be found in cavities under the surface of partially transparent evaporitic minerals that provide them a shelter from the hostile surrounding environment. For influencing the intensity of Raman bands the thickness of covering crystals is not as important as is the actual concentration of the biomarkers. This work and similar experiments serve for better evaluation of Raman spectroscopy as a method for future planetary exploration mission adoption.
  • In this study the possibility to detect biomarkers in experimentally prepared evaporitic matrices using a portable Raman instrument was estimated. Testing of the instrument was carried-out under the Alpine conditions outdoors at a low ambient temperature of -10 degrees C and at an altitude of 2860 m (Pitztal, Austria). Amino acids glycine and L-alanine, nucleo bases thymine and adenine, and metabolite urea were the organics mixed with gypsum powder. In this step it was shown that portable Raman spectroscopic instrumentation is capable of detecting biomarkers in complex samples in a host geological matrix. Such detection is possible even when the laser beam was focussed through the gypsum crystals 3-9 mm thick. For exobiology areas, this is an important fact, because life and/or related biomolecules are likely to be found in cavities under the surface of partially transparent evaporitic minerals that provide them a shelter from the hostile surrounding environment. For influencing the intensity of Raman bands the thickness of covering crystals is not as important as is the actual concentration of the biomarkers. This work and similar experiments serve for better evaluation of Raman spectroscopy as a method for future planetary exploration mission adoption. (en)
Title
  • Testing a portable Raman instrument: The detection of biomarkers in gypsum powdered matrix under gypsum crystals
  • Testing a portable Raman instrument: The detection of biomarkers in gypsum powdered matrix under gypsum crystals (en)
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  • Testing a portable Raman instrument: The detection of biomarkers in gypsum powdered matrix under gypsum crystals
  • Testing a portable Raman instrument: The detection of biomarkers in gypsum powdered matrix under gypsum crystals (en)
skos:notation
  • RIV/00216208:11310/12:10128299!RIV13-GA0-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP210/10/0467), S, Z(MSM0021620855)
http://linked.open...iv/cisloPeriodika
  • FEBRUARY
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 174011
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/12:10128299
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Alpine conditions; Raman spectroscopy; portable; gypsum crystal; Biomarker (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [E8BB52278925]
http://linked.open...i/riv/nazevZdroje
  • Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 86
http://linked.open...iv/tvurceVysledku
  • Culka, Adam
  • Jehlička, Jan
  • Strnad, Ladislav
http://linked.open...ain/vavai/riv/wos
  • 000300515500050
http://linked.open...n/vavai/riv/zamer
issn
  • 1386-1425
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.saa.2011.10.047
http://localhost/t...ganizacniJednotka
  • 11310
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