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  • In this paper Raman spectra were obtained for a series of zeolites (thomsonite, stilbite, natrolite) and beryllium containing silicates (beryl, chrysoberyl, euclase, phenacite, bavenite, milarite) using a portable Raman specrometer with a 785 nm laser excitation to show the possibility to apply this setting for unambiguous detection and discrimination of these silicate minerals. Obtained spectra contain the most intense Raman bands at the same positions 12-4 cm(-1) as reported in the literature. The use of these bands permits the unambiguous identification of these phases. Data show the possibility to discriminate individual species of similar whitish color and aspect. Measurements showed an excellent correspondence of Raman bands obtained using the portable system and a laboratory Raman microspectrometer (with the same excitation laser wavelenght). However, for several minerals of these groups (chrysoberyl, bertrandite, chiavennite) Raman spectra were not of sufficient quality to permit unambiguous identification. The reasons are discussed. Raman spectrum of chiavennite CaMnBe2Si5O13(OH)(2)center dot 2(H2O) - a transformation product occurring together with bavenite on the surface of beryl crystals was obtained for the first time using the laboratory Raman spectrometer.
  • In this paper Raman spectra were obtained for a series of zeolites (thomsonite, stilbite, natrolite) and beryllium containing silicates (beryl, chrysoberyl, euclase, phenacite, bavenite, milarite) using a portable Raman specrometer with a 785 nm laser excitation to show the possibility to apply this setting for unambiguous detection and discrimination of these silicate minerals. Obtained spectra contain the most intense Raman bands at the same positions 12-4 cm(-1) as reported in the literature. The use of these bands permits the unambiguous identification of these phases. Data show the possibility to discriminate individual species of similar whitish color and aspect. Measurements showed an excellent correspondence of Raman bands obtained using the portable system and a laboratory Raman microspectrometer (with the same excitation laser wavelenght). However, for several minerals of these groups (chrysoberyl, bertrandite, chiavennite) Raman spectra were not of sufficient quality to permit unambiguous identification. The reasons are discussed. Raman spectrum of chiavennite CaMnBe2Si5O13(OH)(2)center dot 2(H2O) - a transformation product occurring together with bavenite on the surface of beryl crystals was obtained for the first time using the laboratory Raman spectrometer. (en)
Title
  • Discrimination of zeolites and beryllium containing silicates using portable Raman spectroscometric equipment with near-infrared excitation
  • Discrimination of zeolites and beryllium containing silicates using portable Raman spectroscometric equipment with near-infrared excitation (en)
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  • Discrimination of zeolites and beryllium containing silicates using portable Raman spectroscometric equipment with near-infrared excitation
  • Discrimination of zeolites and beryllium containing silicates using portable Raman spectroscometric equipment with near-infrared excitation (en)
skos:notation
  • RIV/00216208:11310/12:10128072!RIV13-GA0-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP210/10/0467), Z(MSM0021620855)
http://linked.open...iv/cisloPeriodika
  • FEBRUARY
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 131482
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  • RIV/00216208:11310/12:10128072
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  • portable instrumentation; Raman spectroscopy; Be-containing silicates; berylates; Zeolites (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [BC668FEFE3C6]
http://linked.open...i/riv/nazevZdroje
  • Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 86
http://linked.open...iv/tvurceVysledku
  • Jehlička, Jan
  • Vandenabeele, P.
  • Edwards, H. G. M.
http://linked.open...ain/vavai/riv/wos
  • 000300515500049
http://linked.open...n/vavai/riv/zamer
issn
  • 1386-1425
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.saa.2011.10.046
http://localhost/t...ganizacniJednotka
  • 11310
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