About: Coassembly of Poly(ethylene oxide)-block-poly(methacrylic acid) and N-Dodecylpyridinium Chloride in Aqueous Solutions Leading to Ordered Micellar Assemblies within Copolymer Aggregates     Goto   Sponge   NotDistinct   Permalink

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Description
  • Formation of polyelectrolyteMINUS SIGN surfactant (PEMINUS SIGN S) complexes of poly(ethylene oxide)-block-poly(methacrylic acid) (PEO705MINUS SIGN PMAA476) and N-dodecylpyridinium chloride (DPCl) in aqueous solution was studied by static and dynamic light scattering (SLS, DLS), small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), and cryogenic transmission electron microscopy (cryo-TEM). While it was found previously [Macromolecules 1997, 30, 3519] by microcalorimetric titration that in a similar system (PEO176MINUS SIGN PMAA186) crystallization of aliphatic tails of N-dodecylpyridinium bromide did not occur, in our system it was evidenced by SAXS that upon addition of DPCl to fully ionized PEO705MINUS SIGN PMAA476 the ordered arrangement of the surfactant occurs in a certain range of PEO705MINUS SIGN PMAA476 concentrations and surfactant-to-polyelectrolyte charge molar ratio.
  • Formation of polyelectrolyteMINUS SIGN surfactant (PEMINUS SIGN S) complexes of poly(ethylene oxide)-block-poly(methacrylic acid) (PEO705MINUS SIGN PMAA476) and N-dodecylpyridinium chloride (DPCl) in aqueous solution was studied by static and dynamic light scattering (SLS, DLS), small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), and cryogenic transmission electron microscopy (cryo-TEM). While it was found previously [Macromolecules 1997, 30, 3519] by microcalorimetric titration that in a similar system (PEO176MINUS SIGN PMAA186) crystallization of aliphatic tails of N-dodecylpyridinium bromide did not occur, in our system it was evidenced by SAXS that upon addition of DPCl to fully ionized PEO705MINUS SIGN PMAA476 the ordered arrangement of the surfactant occurs in a certain range of PEO705MINUS SIGN PMAA476 concentrations and surfactant-to-polyelectrolyte charge molar ratio. (en)
Title
  • Coassembly of Poly(ethylene oxide)-block-poly(methacrylic acid) and N-Dodecylpyridinium Chloride in Aqueous Solutions Leading to Ordered Micellar Assemblies within Copolymer Aggregates
  • Coassembly of Poly(ethylene oxide)-block-poly(methacrylic acid) and N-Dodecylpyridinium Chloride in Aqueous Solutions Leading to Ordered Micellar Assemblies within Copolymer Aggregates (en)
skos:prefLabel
  • Coassembly of Poly(ethylene oxide)-block-poly(methacrylic acid) and N-Dodecylpyridinium Chloride in Aqueous Solutions Leading to Ordered Micellar Assemblies within Copolymer Aggregates
  • Coassembly of Poly(ethylene oxide)-block-poly(methacrylic acid) and N-Dodecylpyridinium Chloride in Aqueous Solutions Leading to Ordered Micellar Assemblies within Copolymer Aggregates (en)
skos:notation
  • RIV/00216208:11310/12:10123866!RIV13-GA0-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP106/12/0143), P(GAP208/10/0353), P(GCP205/11/J043), P(GPP208/12/P236), Z(AV0Z40500505), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 16
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 127576
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/12:10123866
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • soft matter; SAXS; CryoTEM electron microscopy (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [CF0C60274C2D]
http://linked.open...i/riv/nazevZdroje
  • Macromolecules
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 45
http://linked.open...iv/tvurceVysledku
  • Procházka, Karel
  • Uchman, Mariusz Marcin
  • Štěpánek, Miroslav
  • Angelov, Borislav
  • Appavou, Marie-Sousai
  • Bednar, Jan
  • Gradzielski, Michael
  • Prevost, Sylvain
http://linked.open...ain/vavai/riv/wos
  • 000307988500018
http://linked.open...n/vavai/riv/zamer
issn
  • 0024-9297
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/ma301510j
http://localhost/t...ganizacniJednotka
  • 11310
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