About: Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://dx.doi.org/10.1107/S160053681103621X
Description	The molecular geometry of the complex cation in the title structure, [(mu-Cl)(3){Ru(II)(eta(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) salt [Pandey et al. (1999). J. Organomet. Chem. 592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetrahedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891 (7)-2.2018 (8) angstrom and 107.10 (3)-110.56 (3)degrees, respectively. There are no significant intermolecular interactions in the crystal except for some weak C-H...Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic interactions between the ionic constituents. The molecular geometry of the complex cation in the title structure, [(mu-Cl)(3){Ru(II)(eta(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) salt [Pandey et al. (1999). J. Organomet. Chem. 592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetrahedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.1891 (7)-2.2018 (8) angstrom and 107.10 (3)-110.56 (3)degrees, respectively. There are no significant intermolecular interactions in the crystal except for some weak C-H...Cl contacts, which in turn indicates that the crystal packing is determined predominantly by electrostatic interactions between the ionic constituents. (en)
Title	Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III) Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III) (en)
skos:prefLabel	Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III) Tri-mu-chlorido-bis[(eta(6)-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III) (en)
skos:notation	RIV/00216208:11310/11:10099641!RIV12-MSM-11310___
http://linked.open...avai/riv/aktivita	S Z
http://linked.open...avai/riv/aktivity	S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Schulz, Jiří Císařová, Ivana Štěpnička, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	236100
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/11:10099641
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Structure elucidation; Iron complexes; Arene-ruthenium complexes (en)
http://linked.open.../riv/klicoveSlovo	Arene-ruthenium complexes Iron complexes Structure elucidation
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[EA0FE9C5A85F]
http://linked.open...i/riv/nazevZdroje	Acta Crystallographica Section E: Structure Reports Online
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	67
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Schulz, Jiří Štěpnička, Petr
http://linked.open...ain/vavai/riv/wos	000295614800040
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1600-5368
number of pages	2 (xsd:int)
http://bibframe.org/vocab/doi	10.1107/S160053681103621X
http://localhost/t...ganizacniJednotka	11310

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