About: Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Two novel methods for determination of binding constants in the systems with borate and cyclodextrin complexation were developed. The methods enable to determine all binding parameters in these systems and even the binding constants of interaction of a neutral analyte with a neutral cyclodextrin. The first method is based on nonlinear fitting of experimental data and further evaluation of fitting parameters. The second method requires a multiple regression. The methods provide identical results with low experimental error. Only one set of measurements is required for both methods. Thus the binding parameters can be mutually compared. The binding parameters for neutral analytes ((R,R)-(+)-hydrobenzoin and (S,S)-(-)-hydrobenzoin) and neutral cyclodextrin (heptakis(2,6-di-O-methyl)-beta-cyclodextrin) were evaluated and the effect of individual types of interaction was revealed. Two novel methods for determination of binding constants in the systems with borate and cyclodextrin complexation were developed. The methods enable to determine all binding parameters in these systems and even the binding constants of interaction of a neutral analyte with a neutral cyclodextrin. The first method is based on nonlinear fitting of experimental data and further evaluation of fitting parameters. The second method requires a multiple regression. The methods provide identical results with low experimental error. Only one set of measurements is required for both methods. Thus the binding parameters can be mutually compared. The binding parameters for neutral analytes ((R,R)-(+)-hydrobenzoin and (S,S)-(-)-hydrobenzoin) and neutral cyclodextrin (heptakis(2,6-di-O-methyl)-beta-cyclodextrin) were evaluated and the effect of individual types of interaction was revealed. (en)
Title	Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation (en)
skos:prefLabel	Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation (en)
skos:notation	RIV/00216208:11310/11:10099392!RIV12-GA0-11310___
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1428), S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	40
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Dubský, Pavel Gaš, Bohuslav Svobodová, Jana Tesařová, Eva Beneš, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	211810
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/11:10099392
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Electrophoresis; Binding constants; Complexation; Cyclodextrin; Borate complexation (en)
http://linked.open.../riv/klicoveSlovo	Cyclodextrin Complexation Electrophoresis Binding constants Borate complexation
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[8A25726B9FEE]
http://linked.open...i/riv/nazevZdroje	Journal of Chromatography A
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Capillary electrophoresis with multidimensinal detection and its application to separation and characterization of biopolymers
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	1218
http://linked.open...iv/tvurceVysledku	Dubský, Pavel Gaš, Bohuslav Svobodová, Jana Tesařová, Eva Beneš, Martin
http://linked.open...ain/vavai/riv/wos	000295300600017
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0021-9673
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.chroma.2011.07.088
http://localhost/t...ganizacniJednotka	11310

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