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Description
  • The stepwise syntheses of large [4+4] electron-rich thiamacrocycles, were performed using two types of building blocks, viz. 1,4-bis(bromomethyl)benzene or its dibutoxylated analogue and 4,5-bis(cyanoethylthio)-1,3-dithiol-2-thione. Alternatively, a multicomponent mixture of thiamacrocycles reaching in size from [2+2] to [6+6] units was generated a in a direct reaction of the bis(tetraethylammonium) bis(thioxo-1,3-dithiole-4,5-dithiol) zincate with 2,5-dibutoxy-1,4-bis(bromomethyl)-benzene.
  • The stepwise syntheses of large [4+4] electron-rich thiamacrocycles, were performed using two types of building blocks, viz. 1,4-bis(bromomethyl)benzene or its dibutoxylated analogue and 4,5-bis(cyanoethylthio)-1,3-dithiol-2-thione. Alternatively, a multicomponent mixture of thiamacrocycles reaching in size from [2+2] to [6+6] units was generated a in a direct reaction of the bis(tetraethylammonium) bis(thioxo-1,3-dithiole-4,5-dithiol) zincate with 2,5-dibutoxy-1,4-bis(bromomethyl)-benzene. (en)
Title
  • Synthesis of Electron-Rich Thiamacrocycles
  • Synthesis of Electron-Rich Thiamacrocycles (en)
skos:prefLabel
  • Synthesis of Electron-Rich Thiamacrocycles
  • Synthesis of Electron-Rich Thiamacrocycles (en)
skos:notation
  • RIV/00216208:11310/10:10110801!RIV12-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA400550704), Z(AV0Z40550506), Z(MSM0021620857), Z(MSM6046137301)
http://linked.open...iv/cisloPeriodika
  • 24
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 291527
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/10:10110801
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • thiols; arenes; macrocycles; atropoisomerism; alkylation (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [5067F8E316E0]
http://linked.open...i/riv/nazevZdroje
  • Synthesis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • neuveden
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Hodačová, Jana
  • Holý, Petr
  • Rybáček, Jiří
  • Buchta, Michal
http://linked.open...ain/vavai/riv/wos
  • 000286479200003
http://linked.open...n/vavai/riv/zamer
issn
  • 0039-7881
number of pages
http://bibframe.org/vocab/doi
  • 10.1055/s-0030-1258297
http://localhost/t...ganizacniJednotka
  • 11310
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