About: Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The decavanadate with a novel glycine-glycinato complex of copper (II) in the cationic part, (NH4)(2)(Cu-2 (H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28 center dot 6H(2)O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O- and monodentate O- coordination of glycine to the same central atom was observed for the first time. The decavanadate with a novel glycine-glycinato complex of copper (II) in the cationic part, (NH4)(2)(Cu-2 (H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28 center dot 6H(2)O (1), has been prepared and characterized by elemental analysis, infrared and EPR spectroscopies. The triplet X band EPR spectrum of powdered sample evidenced magnetic interaction between the Cu(II) atoms in the dimeric unit which is probably realized through the bridging water molecules in this part of the complex. A single crystal X-ray diffraction study revealed that the structure of 1 contains cationic copper complex with a rare Cu(H2O)2Cu double bridge. In this cation, a simultaneous bidentate N, O- and monodentate O- coordination of glycine to the same central atom was observed for the first time. (en)
Title	Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O (en)
skos:prefLabel	Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O Synthesis, structure and characterization of (NH4)(2)[Cu-2(H2O)(4)(NH3CH2COO)(2)(NH2CH2COO)(2)]H2V10O28.6H(2)O (en)
skos:notation	RIV/00216208:11310/10:10081686!RIV11-MSM-11310___
http://linked.open...avai/riv/aktivita	V
http://linked.open...avai/riv/aktivity	V
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Gyepes, Robert
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	291566
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/10:10081686
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	EPR; X-ray structure; Copper (II); Glycinato complex; Decavanadate (en)
http://linked.open.../riv/klicoveSlovo	Copper (II) Decavanadate Glycinato complex EPR X-ray structure
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[3736946D05AD]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communication
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	13
http://linked.open...iv/tvurceVysledku	Schwendt, Peter Rakovský, Erik Gyepes, Róbert Klištincová, Lenka Plesch, Gustav
http://linked.open...ain/vavai/riv/wos	000282867800012
issn	1387-7003
number of pages	3 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 36 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software