About: Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2]

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About: Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands were obtained by reduction of tetramethyl(perfluoroalkyl)rhodium(III) dichloro dimers by zinc in THF or by propan-2-ol/sodium carbonate in the presence of the ligands. During the reduction in the presence of ethylene, a new tetramethyl(perfluoroalkyl)-eta-4-cyclopentadiene complex was observed by NMR. This compound, formed by hydrogen transfer from the metal to the ligand, is probably in an equilibrium with the parent hydridocyclopentadienyl complex. Crystal and molecular structure of dicarbonyltetramethyl(perfluorohexyl)cyclopentadienylrhodium(I) complex was determined by X-ray diffraction. Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands were obtained by reduction of tetramethyl(perfluoroalkyl)rhodium(III) dichloro dimers by zinc in THF or by propan-2-ol/sodium carbonate in the presence of the ligands. During the reduction in the presence of ethylene, a new tetramethyl(perfluoroalkyl)-eta-4-cyclopentadiene complex was observed by NMR. This compound, formed by hydrogen transfer from the metal to the ligand, is probably in an equilibrium with the parent hydridocyclopentadienyl complex. Crystal and molecular structure of dicarbonyltetramethyl(perfluorohexyl)cyclopentadienylrhodium(I) complex was determined by X-ray diffraction. (en)
Title	Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] (en)
skos:prefLabel	Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(I) Complexes with Ethylene or Diene Ligands. Crystal Structure of [(eta-5-C5Me4C6F13)Rh(CO)2] (en)
skos:notation	RIV/00216208:11310/10:10057164!RIV11-MSM-11310___
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(IAA4072203), P(LC06070), S, Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika	3
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Císařová, Ivana Vojtíšek, Pavel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	292565
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/10:10057164
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	alkene complexes; rhodium complexes; fluorous cyclopentadienes (en)
http://linked.open.../riv/klicoveSlovo	alkene complexes fluorous cyclopentadienes rhodium complexes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[7373D2E7C432]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Novel fluorophilic ligands for transition metal complexes based on polyfluorinated The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	695
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Krupková, Alena Čermák, Jan Vojtíšek, Pavel Auerová, Kateřina Thi, Thu Huong Nguyen Zámrzla, Milan
http://linked.open...ain/vavai/riv/wos	000273782000010
http://linked.open...n/vavai/riv/zamer	Investigation of multiphase reacting systems for the design of processes important in synthesis and preparation of novel materials, in energy production and in environmental protection
issn	0022-328X
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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