About: Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion     Goto   Sponge   NotDistinct   Permalink

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  • In this communication, we report the synthesis and crystallographic characterization of a rare molecular linear trimer composed of Ca2+ and a carboxyphosphonate (hydroxyphosphonoacetate, HPAA), namely Ca-3(HPAA)(2)(H2O)(14). The two HPAA(3-) ligands function as bridges between the three Ca2+ ions. The central Ca2+ center is found in an octahedral environment, whereas the peripheral Ca2+ centers are in an 8-coordinated environment. This Ca-3(HPAA)(2)(H2O)(14) trimer was found to be an effective corrosion inhibitor for carbon steel surfaces at pH 7.3. Furthermore, we have proven by a variety of techniques that the identity of the anticorrosion film is the same as the rationally synthesized Ca-3(HPAA)(2)(H2O)(14).
  • In this communication, we report the synthesis and crystallographic characterization of a rare molecular linear trimer composed of Ca2+ and a carboxyphosphonate (hydroxyphosphonoacetate, HPAA), namely Ca-3(HPAA)(2)(H2O)(14). The two HPAA(3-) ligands function as bridges between the three Ca2+ ions. The central Ca2+ center is found in an octahedral environment, whereas the peripheral Ca2+ centers are in an 8-coordinated environment. This Ca-3(HPAA)(2)(H2O)(14) trimer was found to be an effective corrosion inhibitor for carbon steel surfaces at pH 7.3. Furthermore, we have proven by a variety of techniques that the identity of the anticorrosion film is the same as the rationally synthesized Ca-3(HPAA)(2)(H2O)(14). (en)
Title
  • Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion
  • Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion (en)
skos:prefLabel
  • Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion
  • Single-Crystalline Thin Films by a Rare Molecular Calcium Carboxyphosphonate Trimer Offer Prophylaxis From Metallic Corrosion (en)
skos:notation
  • RIV/00216208:11310/10:10057086!RIV11-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 287557
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/10:10057086
http://linked.open...riv/jazykVysledku
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  • 3D; 1D; hybrids; surfaces; frameworks; dissolution; osteocalcin; phosphonates; inhibition (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [BC0C979F0FDC]
http://linked.open...i/riv/nazevZdroje
  • ACS Applied Materials & Interfaces
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 2
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Demadis, Konstantinos
  • Papadaki, Maria
http://linked.open...ain/vavai/riv/wos
  • 000280367000007
http://linked.open...n/vavai/riv/zamer
issn
  • 1944-8244
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  • 11310
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