Attributes | Values |
---|
rdf:type
| |
Description
| - Complexes trans-H6do2a2p (H6L)with transition metal and lanthanide(III) ions were investigated. Values of stability constants complexes are intermediate in the ligand series as a consequence of this ligand basicity. The solid-state structures of the ligand and nine lanthanide(III) complexes were determined by X-ray diffraction. The formation kinetics and the acid-assisted dissociation of several Ln(III)-H6L complexes were investigated. According to the 1H NMR pseudo-contact shifts for the Ce-Eu and Tb-Yb series, the solution structures of the complexes reflect the structures of the [Ce(HL)(H2O)]2- and [Yb(HL)]2- anions, respectively, found in the solid state. However, these solution NMR studies showed that there is no unambiguous relation between 31P/1H lanthanide induced shift (LIS) values and coordination of water in the complexes.
- Complexes trans-H6do2a2p (H6L)with transition metal and lanthanide(III) ions were investigated. Values of stability constants complexes are intermediate in the ligand series as a consequence of this ligand basicity. The solid-state structures of the ligand and nine lanthanide(III) complexes were determined by X-ray diffraction. The formation kinetics and the acid-assisted dissociation of several Ln(III)-H6L complexes were investigated. According to the 1H NMR pseudo-contact shifts for the Ce-Eu and Tb-Yb series, the solution structures of the complexes reflect the structures of the [Ce(HL)(H2O)]2- and [Yb(HL)]2- anions, respectively, found in the solid state. However, these solution NMR studies showed that there is no unambiguous relation between 31P/1H lanthanide induced shift (LIS) values and coordination of water in the complexes. (en)
|
Title
| - Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10- tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series
- Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10- tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series (en)
|
skos:prefLabel
| - Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10- tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series
- Lanthanide(III) Complexes of 4,10-Bis(phosphonomethyl)-1,4,7,10- tetraazacyclododecane-1,7-diacetic acid (trans-H6do2a2p) in Solution and in the Solid State: Structural Studies Along the Series (en)
|
skos:notation
| - RIV/00216208:11310/10:10052000!RIV11-GA0-11310___
|
http://linked.open...avai/riv/aktivita
| |
http://linked.open...avai/riv/aktivity
| - P(GA203/09/1056), P(KAN201110651), P(LC06035), P(ME09065), P(OC 179), R, S, V, Z(MSM0021620857)
|
http://linked.open...iv/cisloPeriodika
| |
http://linked.open...vai/riv/dodaniDat
| |
http://linked.open...aciTvurceVysledku
| |
http://linked.open.../riv/druhVysledku
| |
http://linked.open...iv/duvernostUdaju
| |
http://linked.open...titaPredkladatele
| |
http://linked.open...dnocenehoVysledku
| |
http://linked.open...ai/riv/idVysledku
| - RIV/00216208:11310/10:10052000
|
http://linked.open...riv/jazykVysledku
| |
http://linked.open.../riv/klicovaSlova
| - structure elucidation; MRI contrast agents; lanthanides; kinetics; crystal structures (en)
|
http://linked.open.../riv/klicoveSlovo
| |
http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
|
http://linked.open...ontrolniKodProRIV
| |
http://linked.open...i/riv/nazevZdroje
| - Chemistry - A European Journal
|
http://linked.open...in/vavai/riv/obor
| |
http://linked.open...ichTvurcuVysledku
| |
http://linked.open...cetTvurcuVysledku
| |
http://linked.open...vavai/riv/projekt
| |
http://linked.open...UplatneniVysledku
| |
http://linked.open...v/svazekPeriodika
| |
http://linked.open...iv/tvurceVysledku
| - Geraldes, Carlos F. G. C.
- Hermann, Petr
- Kotek, Jan
- Kubíček, Vojtěch
- Lubal, Přemysl
- Vaněk, Jakub
- Tóth, Éva
- Santos, Isabel
- Lacerda, Sara
- Campello, M. Paula C.
- Pereira, Giovannia A.
- Santos, Isabel C.
|
http://linked.open...ain/vavai/riv/wos
| |
http://linked.open...n/vavai/riv/zamer
| |
issn
| |
number of pages
| |
http://localhost/t...ganizacniJednotka
| |