About: Enhanced selectivity in CZE multi-chiral selector enantioseparation systems: Proposed separation mechanism

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About: Enhanced selectivity in CZE multi-chiral selector enantioseparation systems: Proposed separation mechanism Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	It has been reported many times that the commercial mixtures of chiral selectors (CS), namely highly sulfated beta-CDs (HS-beta-CDs), provide remarkable enantioselectivity in CZE when compared with single-isomer CDs, even single-isomer HS-beta-CDs. This enhanced enantioselectivity of multi-CS enantioseparative CZE is discussed in the light of multi-CS model that we have introduced earlier. It is proposed on a theoretical basis and verified experimentally that the two enantiomers of a chiral analyte under interaction with a mixture of CSs are very likely to differ in their limit mobilities, which is opposite to single-CS systems where the two limit mobilities are likely to be the same. It has been reported many times that the commercial mixtures of chiral selectors (CS), namely highly sulfated beta-CDs (HS-beta-CDs), provide remarkable enantioselectivity in CZE when compared with single-isomer CDs, even single-isomer HS-beta-CDs. This enhanced enantioselectivity of multi-CS enantioseparative CZE is discussed in the light of multi-CS model that we have introduced earlier. It is proposed on a theoretical basis and verified experimentally that the two enantiomers of a chiral analyte under interaction with a mixture of CSs are very likely to differ in their limit mobilities, which is opposite to single-CS systems where the two limit mobilities are likely to be the same. (en)
Title	Enhanced selectivity in CZE multi-chiral selector enantioseparation systems: Proposed separation mechanism Enhanced selectivity in CZE multi-chiral selector enantioseparation systems: Proposed separation mechanism (en)
skos:prefLabel	Enhanced selectivity in CZE multi-chiral selector enantioseparation systems: Proposed separation mechanism Enhanced selectivity in CZE multi-chiral selector enantioseparation systems: Proposed separation mechanism (en)
skos:notation	RIV/00216208:11310/10:10001554!RIV11-GA0-11310___
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1428), S, Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Dubský, Pavel Gaš, Bohuslav Svobodová, Jana Tesařová, Eva
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	257228
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/10:10001554
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Multi-chiral selector system; Highly sulfated beta-CD; Enantiomerization; Dynamic chiral separation (en)
http://linked.open.../riv/klicoveSlovo	Dynamic chiral separation Enantiomerization Highly sulfated beta-CD Multi-chiral selector system
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[352DEB2DD9FF]
http://linked.open...i/riv/nazevZdroje	Electrophoresis
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Capillary electrophoresis with multidimensinal detection and its application to separation and characterization of biopolymers
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	31
http://linked.open...iv/tvurceVysledku	Dubský, Pavel Gaš, Bohuslav Svobodová, Jana Tesařová, Eva
http://linked.open...ain/vavai/riv/wos	000277844500003
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0173-0835
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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