About: Reactivity of a C,N-Chelated Stannoxane

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The stannylene {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn (1) did not react with CO2 at room temperature and atmospheric pressure, but its oxidation product {[2-[(CH3)(2)NCH2](2)C6H4](2)Sn-(mu-O)}(2) (2) is very reactive toward CO2 to give the cyclic compound {[2-[(CH3)(2)NCH2](2)C6H4}(2)Sn](2)(mu-O)(mu-CO3) (2b). The product of reaction of 2 with silicon grease is also a cyclic compound with an eight-membered ring, {{{2-[(CH3)(2)NCH2](2)C6H4}(2)Sn}(Me2SiO)}(2) (2c), as the structural characterization revealed (XRD). Triphenylsilanol condensates with 2 to form {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn(OSiPh3)(2) (2b). The reaction of 2 with ethylene glycol gave the cyclic compound {2-[(CH3)(2)-NCH2](2)C6H4}(2)Sn(OCH2CH2O) center dot 1/2(HOCH2CH2OH)(2e). The stannylene {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn (1) did not react with CO2 at room temperature and atmospheric pressure, but its oxidation product {[2-[(CH3)(2)NCH2](2)C6H4](2)Sn-(mu-O)}(2) (2) is very reactive toward CO2 to give the cyclic compound {[2-[(CH3)(2)NCH2](2)C6H4}(2)Sn](2)(mu-O)(mu-CO3) (2b). The product of reaction of 2 with silicon grease is also a cyclic compound with an eight-membered ring, {{{2-[(CH3)(2)NCH2](2)C6H4}(2)Sn}(Me2SiO)}(2) (2c), as the structural characterization revealed (XRD). Triphenylsilanol condensates with 2 to form {2-[(CH3)(2)NCH2](2)C6H4}(2)Sn(OSiPh3)(2) (2b). The reaction of 2 with ethylene glycol gave the cyclic compound {2-[(CH3)(2)-NCH2](2)C6H4}(2)Sn(OCH2CH2O) center dot 1/2(HOCH2CH2OH)(2e). (en)
Title	Reactivity of a C,N-Chelated Stannoxane Reactivity of a C,N-Chelated Stannoxane (en)
skos:prefLabel	Reactivity of a C,N-Chelated Stannoxane Reactivity of a C,N-Chelated Stannoxane (en)
skos:notation	RIV/00216208:11310/09:10001118!RIV10-GA0-11310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/09/0829), P(GA203/07/0468), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Císařová, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	338211
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/09:10001118
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Reactivity; C,N-Chelated; Stannoxane (en)
http://linked.open.../riv/klicoveSlovo	Reactivity C N-Chelated Stannoxane
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[546D2F30A5D5]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Use of Carbon Dioxide as C1 Building Block for Organic Compounds Catalyzed by Metal Containing Compounds Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	28
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Padělková, Zdeňka Růžička, Aleš Vaňkátová, Hana Nechaev, Mikhail Walter, Olaf Zevaco, Thomas
http://linked.open...ain/vavai/riv/wos	000265383700034
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0276-7333
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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