About: Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7). The reactions of a C,N-chelated ((L-CN)(2)M, where L-CN is 2-((dimethylamino)methyl)phenyl and M is Sn (1) or Pb (2)) stannylene and plumbylene with di-n-butylbis(eta(5)-cyclopentadienyl)zirconium (3) were studied. In the case of the stannylene, the trinuclear carbene-like complex [(L-CN)(2)Sn](2)CP2Zr (4) was isolated as the major product. The second product isolated resultedfirom transmetalation of the CN-chelating ligand from tin to zirconium, followed by 1-butene coupling to the coordinated aryne (C,N-chelating ligand) (5). In the lead case, the major product was the complex 5. Byproducts were elemental lead, thefiree ligand ((LH)-H-CN), butane, and 1-butene. The oxidation of 4 by oxygen gave the six- trioxatrizircona cyclic complex (6) and an eight-membered tetraoxa tetrastanna cyclic complex (7). (en)
Title	Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives (en)
skos:prefLabel	Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives Reactions of C,N-chelated Tin(II) and Lead(II) Compounds with Zirconocene Dichloride Derivatives (en)
skos:notation	RIV/00216208:11310/09:10001113!RIV10-GA0-11310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/0468), P(KJB401550802), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Císařová, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	338196
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/09:10001113
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	CNchelatedTin(II); Lead(II)Compounds; ZirconoceneDichlorideDerivatives (en)
http://linked.open.../riv/klicoveSlovo	CNchelatedTin(II) Lead(II)Compounds ZirconoceneDichlorideDerivatives
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[96DCB0F1FE62]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Study of properties and the use of C,N- and Y,C,Y-chelated organometallic compounds LOW VALENT GROUP 14 ORGANOMETALLIC COMPOUNDS, SYNTHESIS, STRUCTURE AND REACTIVITY
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	28
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Padělková, Zdeňka Růžička, Aleš Černošek, Zdeněk Bareš, Josef Pirio, Nadine Philippe, Philippe
http://linked.open...ain/vavai/riv/wos	000266156900023
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0276-7333
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 36 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software