About: C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides

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About: C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Triorganotin(IV) hydrides and cyclopentadienides as well as hexaorganodistannanes containing the moiety L-CN (2-(N,N-dimethylaminomethyl)phenyl-) as chelating ligand and phenyl, n-butyl or t-butyl substituents were prepared and characterized by NMR and XRD. The compounds reveal trigonal bipyramidal geometry around the central tin atom except for the distannanes in which the tin atom has tetrahedral configuration. The di-n-butyl distannane cannot be oxidized by oxygen or heavier chalcogens and give no tin radical when irradiated by UV light or treated with the TEMPO - free radical at room temperature. L-CN(t-Bu)(2)SnH undergoes reaction in solution toward the corresponding distannane. The hydrostannation reaction of L-CN(n-Bu)(2)SnH with ferrocenylacetylene was investigated. The CO2 activation by L-CN(n-Bu)(2)SnH was also examined. Triorganotin(IV) hydrides and cyclopentadienides as well as hexaorganodistannanes containing the moiety L-CN (2-(N,N-dimethylaminomethyl)phenyl-) as chelating ligand and phenyl, n-butyl or t-butyl substituents were prepared and characterized by NMR and XRD. The compounds reveal trigonal bipyramidal geometry around the central tin atom except for the distannanes in which the tin atom has tetrahedral configuration. The di-n-butyl distannane cannot be oxidized by oxygen or heavier chalcogens and give no tin radical when irradiated by UV light or treated with the TEMPO - free radical at room temperature. L-CN(t-Bu)(2)SnH undergoes reaction in solution toward the corresponding distannane. The hydrostannation reaction of L-CN(n-Bu)(2)SnH with ferrocenylacetylene was investigated. The CO2 activation by L-CN(n-Bu)(2)SnH was also examined. (en)
Title	C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides (en)
skos:prefLabel	C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides C,N-chelated hexaorganodistannanes, and triorganotin(IV) hydrides and cyclopentadienides (en)
skos:notation	RIV/00216208:11310/09:10001105!RIV10-GA0-11310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/09/0829), P(KJB401550802), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	18
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Císařová, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	307366
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/09:10001105
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	tin (en)
http://linked.open.../riv/klicoveSlovo	tin
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[BA5B30F267D7]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Use of Carbon Dioxide as C1 Building Block for Organic Compounds Catalyzed by Metal Containing Compounds LOW VALENT GROUP 14 ORGANOMETALLIC COMPOUNDS, SYNTHESIS, STRUCTURE AND REACTIVITY
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	694
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Erben, Milan Padělková, Zdeňka Růžička, Aleš Turek, Jan Černošek, Zdeněk Lyčka, Antonín Nechaev, Mikhail
http://linked.open...ain/vavai/riv/wos	000268265200020
http://linked.open...n/vavai/riv/zamer	Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0022-328X
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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