About: Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium

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About: Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Thermolysis of [TiMe2(eta(5)-C5Me4Ph)(2)] (4) at 145 degrees C for 5 h afforded the singly tucked-in paramagnetictitanocene [Ti(III)(eta(5)-C5Me4Ph){eta(5):eta(1)-C5Me3Ph(CH2)}] (9). In distinction to the singly tucked-in permethyltitanocene [Ti(III)(eta(5)-C5Me5)(eta(5):eta(1)-C5Me4(CH2))] (1) which was found crystallographically disordered [J.M. Fischer, W.E. Piers, V.G. Young, Jr., Organometallics 15 (1996) 2410] the single crystal X-ray diffraction analysis of 9 afforded molecular parameters with nearly by one order better precision as measured by esd-values. Thermolysis of [TiMe2(eta(5)-C5Me4Ph)(2)] (4) at 145 degrees C for 5 h afforded the singly tucked-in paramagnetictitanocene [Ti(III)(eta(5)-C5Me4Ph){eta(5):eta(1)-C5Me3Ph(CH2)}] (9). In distinction to the singly tucked-in permethyltitanocene [Ti(III)(eta(5)-C5Me5)(eta(5):eta(1)-C5Me4(CH2))] (1) which was found crystallographically disordered [J.M. Fischer, W.E. Piers, V.G. Young, Jr., Organometallics 15 (1996) 2410] the single crystal X-ray diffraction analysis of 9 afforded molecular parameters with nearly by one order better precision as measured by esd-values. (en)
Title	Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium (en)
skos:prefLabel	Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium Synthesis and crystal structure of the singly tucked-in derivative of bis(phenyltetramethylcyclopentadienyl)titanium (en)
skos:notation	RIV/00216208:11310/09:10001002!RIV10-MSM-11310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA400400708), P(LC06070), P(LC06071), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Císařová, Ivana
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	345069
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/09:10001002
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	titanium; titanocene; tucked-in (en)
http://linked.open.../riv/klicoveSlovo	titanium tucked-in titanocene
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[CE9F7527A0D1]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	Quasioptical Systems and Terahertz Spectroscopy Activation of small molecules by titanocene(II) and zirconocene(II) complexes. The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	12
http://linked.open...iv/tvurceVysledku	Císařová, Ivana Mach, Karel Pinkas, Jiří Horáček, Michal Kubišta, Jiří Conde, A. Fandos, R.
http://linked.open...ain/vavai/riv/wos	000262891400004
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1387-7003
number of pages	4 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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