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  • The stannylene {2-[(CH3)(2)NCH2]C6H4}(2)Sn (1) was reacted with oxygen, sulfur, selenium, tellurium, and carbon disulfide. The reactions with heavier chalcogens led to the rapid formation of 1:1 dinuclear adducts which were characterized by elemental analysis, ESI-MS measurements, H-1 NMR spectroscopy, and structurally characterized by X-ray diffraction (in the case of reaction products with S-8 (3) and Te (5)). The reaction of 1 with carbon disulfide and elemental sulfur yields the remarkable compound {{2-[(CH3)(2)NCH2](2)C6H4}Sn}(2)(mu(2)-S2C=CS2) (3a). The stability and reactivity of compounds 1-5 were rationalized at DFT/TZ2P level
  • The stannylene {2-[(CH3)(2)NCH2]C6H4}(2)Sn (1) was reacted with oxygen, sulfur, selenium, tellurium, and carbon disulfide. The reactions with heavier chalcogens led to the rapid formation of 1:1 dinuclear adducts which were characterized by elemental analysis, ESI-MS measurements, H-1 NMR spectroscopy, and structurally characterized by X-ray diffraction (in the case of reaction products with S-8 (3) and Te (5)). The reaction of 1 with carbon disulfide and elemental sulfur yields the remarkable compound {{2-[(CH3)(2)NCH2](2)C6H4}Sn}(2)(mu(2)-S2C=CS2) (3a). The stability and reactivity of compounds 1-5 were rationalized at DFT/TZ2P level (en)
Title
  • Reactivity of a C,N-chelated stannylene with chalcogens
  • Reactivity of a C,N-chelated stannylene with chalcogens (en)
skos:prefLabel
  • Reactivity of a C,N-chelated stannylene with chalcogens
  • Reactivity of a C,N-chelated stannylene with chalcogens (en)
skos:notation
  • RIV/00216208:11310/09:10000510!RIV10-GA0-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/07/0468), P(KJB401550802), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 338212
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/09:10000510
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • tin; chalcogens (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [6402D491E6C1]
http://linked.open...i/riv/nazevZdroje
  • Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 694
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Nechaev, Mikhail
http://linked.open...ain/vavai/riv/wos
  • 000268265200001
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-328X
number of pages
http://localhost/t...ganizacniJednotka
  • 11310
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