About: Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide)

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About: Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position. Two new neutral monoperoxidovanadium(V) complexes [VO(O-2)(L)(pa)]center dot xH(2)O have been synthesized: [VO(O-2)(pic)(pa)]center dot H2O (1) and [VO(O-2)(Hquin)(pa)]center dot 2H(2)O (2) [pic: pyridine-2-carboxylato(1-) or picolinato(1-), Hquin: pyridine-2,3-dicarboxylato(1-) or quinolinato(1-), and pa: picolinamide]. The solid state structures of 1 and 2 feature a typical distorted pentagonal bipyramid coordination polyhedron around the central vanadium atoms. The bidentate anionic ligands are coordinated in two equatorial positions, while the bidentate picolinamide molecule is bound via the aromatic nitrogen and the carboxamide oxygen in one equatorial and one apical position. (en)
Title	Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) (en)
skos:prefLabel	Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) Experimental and computational evidence of solid-state anion-pi and pi-pi interactions in [VO(O-2)(L)(pa)]center dot xH(2)O complexes (L = picolinate, pyrazinate or quinolinate; pa = picolinamide) (en)
skos:notation	RIV/00216208:11310/09:10000304!RIV11-MSM-11310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	33
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Gyepes, Robert
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Karlova v Praze / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	314187
http://linked.open...ai/riv/idVysledku	RIV/00216208:11310/09:10000304
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	stereochemistry; ligands; mandelic-acid; peroxo complexes; peroxovanadium complexes; supramolecular interactions; vanadium(v) oxo; coordination polymers; crystal-structure; Oxo-monoperoxo complexes (en)
http://linked.open.../riv/klicoveSlovo	coordination polymers ligands crystal-structure stereochemistry supramolecular interactions peroxo complexes peroxovanadium complexes Oxo-monoperoxo complexes mandelic-acid vanadium(v) oxo
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[8EAD0648BCBF]
http://linked.open...i/riv/nazevZdroje	New Journal of Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	2009
http://linked.open...iv/tvurceVysledku	Gyepes, Róbert Pacigová, Silvia Sivák, Michal Tatiersky, Jozef
http://linked.open...ain/vavai/riv/wos	000267728200012
http://linked.open...n/vavai/riv/zamer	Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1144-0546
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	11310

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