About: Dibromido(eta(5),eta(5)-propane-2,2-diyl-dicyclopentadienyl)titanium(IV)     Goto   Sponge   NotDistinct   Permalink

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Description
  • In the molecule of the title compound, [TiBr2(C13H14)], the Ti-IV centre is in a distorted tetrahedral environment involving two eta(5)-bonded cyclopentadienyl rings of a propane-2,2-diyldicyclopentadienyl ligand [Ti -Cg = 2.045 (2) angstrom; Cg is the centroid of the cyclopentadienyl ring] and two Br atoms [Ti-Br = 2.5115 (7) angstrom]. The presence of the short 2,2-propylidene bridge between the two cyclopentadienyl rings constrains the Cg-Ti-Cg angle to a value of 121.32 (9)degrees. The Ti and central C atoms are located on a crystallographic C-2 axis.
  • In the molecule of the title compound, [TiBr2(C13H14)], the Ti-IV centre is in a distorted tetrahedral environment involving two eta(5)-bonded cyclopentadienyl rings of a propane-2,2-diyldicyclopentadienyl ligand [Ti -Cg = 2.045 (2) angstrom; Cg is the centroid of the cyclopentadienyl ring] and two Br atoms [Ti-Br = 2.5115 (7) angstrom]. The presence of the short 2,2-propylidene bridge between the two cyclopentadienyl rings constrains the Cg-Ti-Cg angle to a value of 121.32 (9)degrees. The Ti and central C atoms are located on a crystallographic C-2 axis. (en)
Title
  • Dibromido(eta(5),eta(5)-propane-2,2-diyl-dicyclopentadienyl)titanium(IV)
  • Dibromido(eta(5),eta(5)-propane-2,2-diyl-dicyclopentadienyl)titanium(IV) (en)
skos:prefLabel
  • Dibromido(eta(5),eta(5)-propane-2,2-diyl-dicyclopentadienyl)titanium(IV)
  • Dibromido(eta(5),eta(5)-propane-2,2-diyl-dicyclopentadienyl)titanium(IV) (en)
skos:notation
  • RIV/00216208:11310/07:10110816!RIV12-MSM-11310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 417081
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/07:10110816
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • dibromido(eta5,eta5-propane-2,2-diyl-dicyclopentadienyl)titanium(IV); crystal strucrure (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [0DB3A9D7C291]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica Section E: Structure Reports Online
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 63
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Dušek, Michal
  • Erben, Milan
  • Vinklárek, Jaromír
  • Picka, Michal
http://linked.open...ain/vavai/riv/wos
  • 000251281800059
issn
  • 1600-5368
number of pages
http://bibframe.org/vocab/doi
  • 10.1107/S1600536807048921
http://localhost/t...ganizacniJednotka
  • 11310
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