About: Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands     Goto   Sponge   NotDistinct   Permalink

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  • (Amidocyclopentadienyl)dichlorotitanium(IV) complexes of the general formula, [TiCl2{h5:h1(N)-C5(1-SiMe2Nt-Bu-2,3,4-Me3-5-R)}], where R = H (6b), Ph (6c), 4-fluorophenyl (6d) and 1-methylallyl (6e) were synthesized and characterized by spectral methods. Solid-state structure of [TiCl2{h5:h1(N)-C5Me4(SiMe2Nt-Bu)}] (6a) and 6d determined by single-crystal X-ray diffraction showed th at variation of the ring substituent R has only a negligible effect(6a) and 6d determined by single-crystal X-ray diffraction showed that variation of the ring substituent R has only a negligible effect on the molecular structure of the complexes.
  • (Amidocyclopentadienyl)dichlorotitanium(IV) complexes of the general formula, [TiCl2{h5:h1(N)-C5(1-SiMe2Nt-Bu-2,3,4-Me3-5-R)}], where R = H (6b), Ph (6c), 4-fluorophenyl (6d) and 1-methylallyl (6e) were synthesized and characterized by spectral methods. Solid-state structure of [TiCl2{h5:h1(N)-C5Me4(SiMe2Nt-Bu)}] (6a) and 6d determined by single-crystal X-ray diffraction showed th at variation of the ring substituent R has only a negligible effect(6a) and 6d determined by single-crystal X-ray diffraction showed that variation of the ring substituent R has only a negligible effect on the molecular structure of the complexes. (en)
Title
  • Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands
  • Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands (en)
skos:prefLabel
  • Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands
  • Synthesis and crystal structures of dimethylsilylene-bridged (amidocyclopentadienyl)dichlorotitanium(IV) complexes with various substituents on the cyclopentadienyl ligands (en)
skos:notation
  • RIV/00216208:11310/01:00107027!RIV/2002/GA0/113102/N
http://linked.open.../vavai/riv/strany
  • 605;610
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/99/0067), P(GA203/99/M037), P(LN00B142)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 698099
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11310/01:00107027
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • titanium; half-sandwich complexes; X-ray diffraction; NMR spectroscopy; alkene polymerization catalysts (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [473DAAFDB617]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 66
http://linked.open...iv/tvurceVysledku
  • Císařová, Ivana
  • Fejfarová, Karla
  • Štěpnička, Petr
  • Gyepes, Róbert
issn
  • 0010-0765
number of pages
http://localhost/t...ganizacniJednotka
  • 11310
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