About: S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study     Goto   Sponge   NotDistinct   Permalink

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Description
  • A series of tri- and diorganotin(IV) compounds containing potentially chelating S,N-ligand(s) (L(SN), where L(SN) is 6-phenylpyridazine-3-thiolate) were prepared and structurally characterized by multinuclear NMR spectroscopy. X-ray diffraction techniques were used for determination of the structure of compounds containing one [(L(SN))Ph(2)SnCl], two [(n-Bu)(2)Sn(L(SN))(2)] and the combination of two L(SN) and one L(CN) [(L(CN))(n-Bu)Sn(L(SN))(2)] (where L(CN) is {2-[(CH(3))(2)NCH(2)]C(6)H(4)}-) ligands. The coordination number of the tin atom varies from five to seven and is dependent on the number of chelating ligands present. The formation of the five-membered azastanna heterocycle is favored over the formation of four-membered azastannathia heterocycle in compounds containing both types of ligands. The di-n-butyl-substituted compounds are the most efficient ones in inhibition of growth of yeasts, molds and G(+) bacteria strains.
  • A series of tri- and diorganotin(IV) compounds containing potentially chelating S,N-ligand(s) (L(SN), where L(SN) is 6-phenylpyridazine-3-thiolate) were prepared and structurally characterized by multinuclear NMR spectroscopy. X-ray diffraction techniques were used for determination of the structure of compounds containing one [(L(SN))Ph(2)SnCl], two [(n-Bu)(2)Sn(L(SN))(2)] and the combination of two L(SN) and one L(CN) [(L(CN))(n-Bu)Sn(L(SN))(2)] (where L(CN) is {2-[(CH(3))(2)NCH(2)]C(6)H(4)}-) ligands. The coordination number of the tin atom varies from five to seven and is dependent on the number of chelating ligands present. The formation of the five-membered azastanna heterocycle is favored over the formation of four-membered azastannathia heterocycle in compounds containing both types of ligands. The di-n-butyl-substituted compounds are the most efficient ones in inhibition of growth of yeasts, molds and G(+) bacteria strains. (en)
Title
  • S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study
  • S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study (en)
skos:prefLabel
  • S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study
  • S,N-Chelated organotin(IV) compounds containing 6-phenylpyridazine-3-thiolate ligand - structural, antibacterial and antifungal study (en)
skos:notation
  • RIV/00216208:11160/11:10118896!RIV12-MSM-11160___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP207/10/0215), S, Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika
  • 10
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http://linked.open...aciTvurceVysledku
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  • 230098
http://linked.open...ai/riv/idVysledku
  • RIV/00216208:11160/11:10118896
http://linked.open...riv/jazykVysledku
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  • antibacterial and fungicidal study; X-ray diffraction analyses; NMR spectroscopy; organotin(IV) compounds (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [156399498D6B]
http://linked.open...i/riv/nazevZdroje
  • Applied Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
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http://linked.open...vavai/riv/projekt
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http://linked.open...v/svazekPeriodika
  • 25
http://linked.open...iv/tvurceVysledku
  • Padělková, Zdeňka
  • Růžička, Aleš
  • Švec, Petr
  • Vejsová, Marcela
  • Holeček, Jaroslav
  • Česlová, Lenka
  • Ozerianskyi, Andrii
  • Vaňkátová, Hana
http://linked.open...ain/vavai/riv/wos
  • 000295294800001
http://linked.open...n/vavai/riv/zamer
issn
  • 0268-2605
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/aoc.1823
http://localhost/t...ganizacniJednotka
  • 11160
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