About: Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes

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About: Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://onlinelibrary.wiley.com/doi/10.1002/elan.201300170/pdf
Description	Protein catalyzed hydrogen evolution reaction at mercury-containing electrodes controlled by constant-current chronopotentiometric stripping (CPS) is representing a new tool useful in protein research. The resulting CPS peak H is sensitive to changes in the protein structure and its amino acid composition. Besides CPS, cyclic voltammetry appears to be useful for study of poly(amino acids) as an intermediate model system between peptides and macromolecular proteins. Here we show that similarly as arginine in polyarginine and lysine in polylysine also histidine residues in polyhistidine contribute to the catalysis of hydrogen evolution under the given conditions. Peak potentials of individual poly(amino acids) are different and depend on the type of amino acid residues. Protein catalyzed hydrogen evolution reaction at mercury-containing electrodes controlled by constant-current chronopotentiometric stripping (CPS) is representing a new tool useful in protein research. The resulting CPS peak H is sensitive to changes in the protein structure and its amino acid composition. Besides CPS, cyclic voltammetry appears to be useful for study of poly(amino acids) as an intermediate model system between peptides and macromolecular proteins. Here we show that similarly as arginine in polyarginine and lysine in polylysine also histidine residues in polyhistidine contribute to the catalysis of hydrogen evolution under the given conditions. Peak potentials of individual poly(amino acids) are different and depend on the type of amino acid residues. (en)
Title	Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes (en)
skos:prefLabel	Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes Catalysis of hydrogen evolution by polylysine, polyarginine and polyhistidine at mercury electrodes (en)
skos:notation	RIV/00209805:_____/13:#0000429!RIV14-GA0-00209805
http://linked.open...avai/riv/aktivita	I P Z
http://linked.open...avai/riv/aktivity	I, P(ED2.1.00/03.0101), P(GA13-00956S), Z(AV0Z50040702)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Paleček, Emil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Masarykův onkologický ústav
http://linked.open...dnocenehoVysledku	64404
http://linked.open...ai/riv/idVysledku	RIV/00209805:_____/13:#0000429
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	catalytic hydrogen evolution; cyclic voltammetry; constant-current chronopotentiometric stripping; mercury electrode; polyamino acids (en)
http://linked.open.../riv/klicoveSlovo	cyclic voltammetry catalytic hydrogen evolution constant-current chronopotentiometric stripping polyamino acids mercury electrode
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[3A32A2DC59A9]
http://linked.open...i/riv/nazevZdroje	Electroanalysis
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Emerging roles for the proteins of Anterior Gradient family in cancer development Regional Centre for Applied Molecular Oncology (RECAMO)
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	25
http://linked.open...iv/tvurceVysledku	Paleček, Emil
http://linked.open...ain/vavai/riv/wos	000327590600015
http://linked.open...n/vavai/riv/zamer	Genome and epigenome: 1D and 3D Structure, Dynamics, Interactions with Proteins and Functions
issn	1040-0397
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/elan.201300170

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