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  • This study focuses attention to the identification of photodegradation products of polyurethane foams with enhanced biodegradability, resulting from partial replacement of synthetic polyols by bio-originated and biodegradable ones during polyurethane synthesis. The tested materials were irradiated by UV-light. Volatile compounds were sorbed during irradiation using SPME and analyzed by comprehensive orthogonal two-dimensional gas chromatography – mass spectrometry (GCxGC/TOF MS). Semivolatile compounds were extracted from exposed polyurethane foam by n-hexane and analyzed by gas chromatography – mass spectrometry (GC/MS). Large number of structurally diverse compounds was detected; most of them were identified. The influence of biodegradable filler on the composition of photodegradation products was also assessed.
  • This study focuses attention to the identification of photodegradation products of polyurethane foams with enhanced biodegradability, resulting from partial replacement of synthetic polyols by bio-originated and biodegradable ones during polyurethane synthesis. The tested materials were irradiated by UV-light. Volatile compounds were sorbed during irradiation using SPME and analyzed by comprehensive orthogonal two-dimensional gas chromatography – mass spectrometry (GCxGC/TOF MS). Semivolatile compounds were extracted from exposed polyurethane foam by n-hexane and analyzed by gas chromatography – mass spectrometry (GC/MS). Large number of structurally diverse compounds was detected; most of them were identified. The influence of biodegradable filler on the composition of photodegradation products was also assessed. (en)
Title
  • Photo-degradation products of polyurethane foam with enhanced biodegradability
  • Photo-degradation products of polyurethane foam with enhanced biodegradability (en)
skos:prefLabel
  • Photo-degradation products of polyurethane foam with enhanced biodegradability
  • Photo-degradation products of polyurethane foam with enhanced biodegradability (en)
skos:notation
  • RIV/00025798:_____/13:00000514!RIV15-MSM-00025798
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I
http://linked.open...iv/cisloPeriodika
  • 8A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 96088
http://linked.open...ai/riv/idVysledku
  • RIV/00025798:_____/13:00000514
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Polyurethane foam, biodegradable filler, photodegradation, SPME, GC/MS, GCxGC/MS (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [8D154B11D728]
http://linked.open...i/riv/nazevZdroje
  • Fresenius Environmental Bulletin
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 22
http://linked.open...iv/tvurceVysledku
  • Vávrová, Milada
  • Čáslavský, Josef
  • Mácová, Daniela
  • Bolechová, Martina
http://linked.open...ain/vavai/riv/wos
  • 000327575500001
issn
  • 1018-4619
number of pages
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