About: Crystallochemical effects of heat treatment on Fe-dominant tourmalines from Dolní Bory (Czech Republic) and Vlachovo (Slovakia)     Goto   Sponge   NotDistinct   Permalink

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  • Heat treatment was performed on selected Fedominant tourmalines to establish the nature of any change in optical properties. Two tourmaline samples from Dolní Bory, Czech Republic (TDB) and Vlachovo, Slovakia (TVL) were heated at 450, 700 and 900°C at 0.1 mPa and ambient oxidation conditions for 8 h. The oxidation of Fe is mostly significant in the Y site as documented on the compression of the Y-site octahedra and subsequent decrease in the a lattice parameter. The Z-site octahedra did not compressed and were not affected by heating-induced Fe oxidation, which indicates only negligible content of ZFe2+ in original samples. After heating at 900°C, the tourmaline structure collapsed likely due to the thermally induced weakening of bonds in Y and Z octahedra, which results in amorphization of tourmaline. Subsequently, breakdown products including Fe-oxides and mullite replaced alkali-depleted amorphized tourmaline.
  • Heat treatment was performed on selected Fedominant tourmalines to establish the nature of any change in optical properties. Two tourmaline samples from Dolní Bory, Czech Republic (TDB) and Vlachovo, Slovakia (TVL) were heated at 450, 700 and 900°C at 0.1 mPa and ambient oxidation conditions for 8 h. The oxidation of Fe is mostly significant in the Y site as documented on the compression of the Y-site octahedra and subsequent decrease in the a lattice parameter. The Z-site octahedra did not compressed and were not affected by heating-induced Fe oxidation, which indicates only negligible content of ZFe2+ in original samples. After heating at 900°C, the tourmaline structure collapsed likely due to the thermally induced weakening of bonds in Y and Z octahedra, which results in amorphization of tourmaline. Subsequently, breakdown products including Fe-oxides and mullite replaced alkali-depleted amorphized tourmaline. (en)
Title
  • Crystallochemical effects of heat treatment on Fe-dominant tourmalines from Dolní Bory (Czech Republic) and Vlachovo (Slovakia)
  • Crystallochemical effects of heat treatment on Fe-dominant tourmalines from Dolní Bory (Czech Republic) and Vlachovo (Slovakia) (en)
skos:prefLabel
  • Crystallochemical effects of heat treatment on Fe-dominant tourmalines from Dolní Bory (Czech Republic) and Vlachovo (Slovakia)
  • Crystallochemical effects of heat treatment on Fe-dominant tourmalines from Dolní Bory (Czech Republic) and Vlachovo (Slovakia) (en)
skos:notation
  • RIV/00025798:_____/11:00000403!RIV12-MZP-00025798
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, Z(MZP0002579801)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 192380
http://linked.open...ai/riv/idVysledku
  • RIV/00025798:_____/11:00000403
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Tourmaline, Heating, Fe oxidation, Disintegration of structure, Electron microprobe, Powder X-ray diffraction, Infrared spectroscopy, Mössbauer spectroscopy, Electron backscatter diffraction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [4E6122B81014]
http://linked.open...i/riv/nazevZdroje
  • Physics and Chemistry of Minerals
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 38
http://linked.open...iv/tvurceVysledku
  • Bačík, P.
  • Haloda, Jakub
  • Kardošová, P.
  • Miglierini, M.
  • Odzín, D.
  • Petrák, M.
http://linked.open...ain/vavai/riv/wos
  • 000293141700003
http://linked.open...n/vavai/riv/zamer
issn
  • 0342-1791
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s00269-011-0432-5
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