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  • The metal-rich portion of the Co-Ni-P system was studied experimentally at 800 oC by means of evacuated silica glass tube technique. Five binary phases: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P and five ternary phosphides solid solutions: (Co1-x, Nix)3P, ?1-(Ni1-xCox)2P (hexagonal), ?2-Co1-xNix)2P (orthorhombic),(Co1-x,Nix)12P5 and (Co1-x,Nix)5P2 were found to be stable in the system. Cobalt has a significant influence on the structure of (Ni,Co)2P solid solutions and, therefore, cobalt contents might change the crystal structure of naturally occurring phosphides with the Ni/P = 2:1 ratio. Ni-rich, cobalt-containing phosphides with the Ni/P ratio = 3:1 and 2:1, isotypic with minerals schreibersite and barringerite, could possibly be found in meteorites. Likewise, phosphides with Ni/P ratio = 12:5 and 5:2 may possibly be found, but in close association with natural Ni-rich phosphides.
  • The metal-rich portion of the Co-Ni-P system was studied experimentally at 800 oC by means of evacuated silica glass tube technique. Five binary phases: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P and five ternary phosphides solid solutions: (Co1-x, Nix)3P, ?1-(Ni1-xCox)2P (hexagonal), ?2-Co1-xNix)2P (orthorhombic),(Co1-x,Nix)12P5 and (Co1-x,Nix)5P2 were found to be stable in the system. Cobalt has a significant influence on the structure of (Ni,Co)2P solid solutions and, therefore, cobalt contents might change the crystal structure of naturally occurring phosphides with the Ni/P = 2:1 ratio. Ni-rich, cobalt-containing phosphides with the Ni/P ratio = 3:1 and 2:1, isotypic with minerals schreibersite and barringerite, could possibly be found in meteorites. Likewise, phosphides with Ni/P ratio = 12:5 and 5:2 may possibly be found, but in close association with natural Ni-rich phosphides. (en)
  • Fázové vztahy v kovy bohaté části soustavy Co-Ni-P byly studovány v zatavených, evakuovaných kamenných trubicích. V soustavě bylo identifikováno pět binárních fází: Co2P, Ni2P, Ni12P5, Ni5P2, Ni3P a pět ternárních pevných roztoku: (Co1-x, Nix)3P, ë1-(Ni1?xCox)2P (hexagonální), ë2-Co1?xNix)2P (ortorombický),(Co1-x,Nix)12P5 a (Co1-x,Nix)5P2. Kobalt má významný vliv na strukturu Ni-Co fosfidu. (cs)
Title
  • The metal-rich part of the Co-Ni-P system at 800 oC
  • Kovem bohatá část soustavy Co-Ni-P při 800 oC. (cs)
  • The metal-rich part of the Co-Ni-P system at 800 oC (en)
skos:prefLabel
  • The metal-rich part of the Co-Ni-P system at 800 oC
  • Kovem bohatá část soustavy Co-Ni-P při 800 oC. (cs)
  • The metal-rich part of the Co-Ni-P system at 800 oC (en)
skos:notation
  • RIV/00025798:_____/06:00000226!RIV07-GA0-00025798
http://linked.open.../vavai/riv/strany
  • 545-550
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA205/05/0459)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
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  • 485052
http://linked.open...ai/riv/idVysledku
  • RIV/00025798:_____/06:00000226
http://linked.open...riv/jazykVysledku
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  • phase relations, phosphides, Co, Ni, P (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [EB12D57D51E8]
http://linked.open...i/riv/nazevZdroje
  • Europ. Journ. of Mineralogy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 5
http://linked.open...iv/tvurceVysledku
  • Drábek, Milan
issn
  • 0935-1221
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