About: Raman and infrared spectroscopic studies of phurcalite from Red Canyon, Utah, USA – Implications for the molecular structure     Goto   Sponge   NotDistinct   Permalink

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  • Raman and infrared spectra of the uranyl mineral phurcalite, Ca2(UO2)(3)O2(PO4)2.7H2O, from Red Canyon, Utah, USA, were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of (UO2)2+ and (PO4)3- units and to the stretching and bending vibrations and libration modes of water molecules. Approximate lengths of U-O in (UO2)2+ and O-H ... O hydrogen bond lengths were inferred from observed stretching vibrations. The presence of structurally nonequivalent U6+ and P5+ was inferred from the number of corresponding stretching bands of (UO2)2+ and (PO4)3) units observed in the Raman and infrared spectra.
  • Raman and infrared spectra of the uranyl mineral phurcalite, Ca2(UO2)(3)O2(PO4)2.7H2O, from Red Canyon, Utah, USA, were studied and tentatively interpreted. Observed bands were assigned to the stretching and bending vibrations of (UO2)2+ and (PO4)3- units and to the stretching and bending vibrations and libration modes of water molecules. Approximate lengths of U-O in (UO2)2+ and O-H ... O hydrogen bond lengths were inferred from observed stretching vibrations. The presence of structurally nonequivalent U6+ and P5+ was inferred from the number of corresponding stretching bands of (UO2)2+ and (PO4)3) units observed in the Raman and infrared spectra. (en)
Title
  • Raman and infrared spectroscopic studies of phurcalite from Red Canyon, Utah, USA – Implications for the molecular structure
  • Raman and infrared spectroscopic studies of phurcalite from Red Canyon, Utah, USA – Implications for the molecular structure (en)
skos:prefLabel
  • Raman and infrared spectroscopic studies of phurcalite from Red Canyon, Utah, USA – Implications for the molecular structure
  • Raman and infrared spectroscopic studies of phurcalite from Red Canyon, Utah, USA – Implications for the molecular structure (en)
skos:notation
  • RIV/00023272:_____/14:#0002395!RIV15-MK0-00023272
http://linked.open...avai/riv/aktivita
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  • June
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  • 41265
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  • RIV/00023272:_____/14:#0002395
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  • phurcalite; Raman spectroscopy; Infrared spectroscopy; mineral (en)
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  • NL - Nizozemsko
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  • [28E666CA1D1B]
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  • Journal of molecular structure
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  • 1068
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  • Frost, Ray Leslie
  • Sejkora, Jiří
  • Čejka, Jiří
  • Scholz, Ricardo
  • Xi, Yunfei
  • López, Andrés
http://linked.open...ain/vavai/riv/wos
  • 000337989800003
issn
  • 0022-2860
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.molstruc.2014.03.040
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