About: Raman spectroscopic study of a hydroxy-arsenate mineral containing bismuth-atelestite Bi2O(OH)(AsO4)     Goto   Sponge   NotDistinct   Permalink

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  • The Raman spectrum of atelestite Bi2O(OH)(AsO4), a hydroxy-arsenate mineral containing bismuth, has been studied in terms of spectra-structure relations. The studied spectrum is compared with the Raman spectrum of atelestite downloaded from the RRUFF database. The sharp intense band at 834 cm-1 is assigned to the v AsO4(3-) symmetric stretching mode and the three bands at 767, 782 and 802 cm-1 to the v3 AsO4(3-) antisymmetric stretching modes. The bands at 310, 324, 353, 370, 395, 450, 480 and 623 cm-1 are assigned to the corresponding v4 and v2 bending modes and Bi-O-Bi (vibration of bridging oxygen) and Bi-O (vibration of non-bridging oxygen) stretching vibrations. Lattice modes are observed at 172,199 and 218 cm-1. A broad low intensity band at 3095 cm-1 is attributed to the hydrogen bonded OH units in the atelestite structure. A weak band at 1082 cm-1 is assigned to delta (Bi-OH) vibration.
  • The Raman spectrum of atelestite Bi2O(OH)(AsO4), a hydroxy-arsenate mineral containing bismuth, has been studied in terms of spectra-structure relations. The studied spectrum is compared with the Raman spectrum of atelestite downloaded from the RRUFF database. The sharp intense band at 834 cm-1 is assigned to the v AsO4(3-) symmetric stretching mode and the three bands at 767, 782 and 802 cm-1 to the v3 AsO4(3-) antisymmetric stretching modes. The bands at 310, 324, 353, 370, 395, 450, 480 and 623 cm-1 are assigned to the corresponding v4 and v2 bending modes and Bi-O-Bi (vibration of bridging oxygen) and Bi-O (vibration of non-bridging oxygen) stretching vibrations. Lattice modes are observed at 172,199 and 218 cm-1. A broad low intensity band at 3095 cm-1 is attributed to the hydrogen bonded OH units in the atelestite structure. A weak band at 1082 cm-1 is assigned to delta (Bi-OH) vibration. (en)
Title
  • Raman spectroscopic study of a hydroxy-arsenate mineral containing bismuth-atelestite Bi2O(OH)(AsO4)
  • Raman spectroscopic study of a hydroxy-arsenate mineral containing bismuth-atelestite Bi2O(OH)(AsO4) (en)
skos:prefLabel
  • Raman spectroscopic study of a hydroxy-arsenate mineral containing bismuth-atelestite Bi2O(OH)(AsO4)
  • Raman spectroscopic study of a hydroxy-arsenate mineral containing bismuth-atelestite Bi2O(OH)(AsO4) (en)
skos:notation
  • RIV/00023272:_____/11:#0001571!RIV12-MK0-00023272
http://linked.open...avai/riv/aktivita
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  • Z(MK00002327201)
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  • 1
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  • 225649
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  • RIV/00023272:_____/11:#0001571
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  • atelestite; arsenate; bismuth; Raman spectroscopy (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [993716AA7BCE]
http://linked.open...i/riv/nazevZdroje
  • Spectrochemica Acta Part A-Molecular and biomolecular spectroscopy
http://linked.open...in/vavai/riv/obor
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  • 78
http://linked.open...iv/tvurceVysledku
  • Frost, Ray Leslie
  • Keeffe, Eloise C.
  • Plášil, Jakub
  • Sejkora, Jiří
  • Čejka, Jiří
  • Reddy, Jagannadha B.
http://linked.open...ain/vavai/riv/wos
  • 000287107000076
http://linked.open...n/vavai/riv/zamer
issn
  • 1386-1425
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.saa.2010.11.016
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