About: A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite     Goto   Sponge   NotDistinct   Permalink

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  • Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH). 2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H ... O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases.
  • Raman and infrared spectra of two polymorphous minerals with the chemical formula Fe3+(SO4)(OH). 2H2O, monoclinic butlerite and orthorhombic parabutlerite, are studied and the spectra assigned. Observed bands are attributed to the (SO4)2- stretching and bending vibrations, hydrogen bonded water molecules, stretching and bending vibrations of hydroxyl ions, water librational modes, Fe-O and Fe-OH stretching vibrations, Fe-OH bending vibrations and lattice vibrations. The O-H ... O hydrogen bond lengths in the structures of both minerals are calculated from the wavenumbers of the stretching vibrations. One symmetrically distinct (SO4)2- unit in the structure of butlerite and two symmetrically distinct (SO4)2- units in the structure of parabutlerite are inferred from the Raman and infrared spectra. This conclusion agrees with the published crystal structures of both mineral phases. (en)
Title
  • A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite
  • A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite (en)
skos:prefLabel
  • A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite
  • A vibrational spectroscopic study of hydrated Fe3+ hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite (en)
skos:notation
  • RIV/00023272:_____/11:#0001564!RIV12-MK0-00023272
http://linked.open...avai/riv/aktivita
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  • I, Z(MK00002327201)
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  • 5
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  • 184251
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  • RIV/00023272:_____/11:#0001564
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  • butlerite; parabutlerite; iron (III) sulfates; Raman spectroscopy; Infrared spectroscopy (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [B0C3E2FEB775]
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  • Spectrochimica Acta Part A-Molecular and biomolecular spectroscopy
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  • 79
http://linked.open...iv/tvurceVysledku
  • Bahfenne, Silmarilly
  • Frost, Ray Leslie
  • Palmer, Sara J.
  • Plášil, Jakub
  • Sejkora, Jiří
  • Čejka, Jiří
http://linked.open...ain/vavai/riv/wos
  • 000293363000076
http://linked.open...n/vavai/riv/zamer
issn
  • 1386-1425
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.saa.2011.04.069
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