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Description
| - Raman and infrared spectroscopies were used to characterise two samples of triclinic cejkaite Na4[UO2(CO3)3] and its synthetic trigonal analogue. The nu3 (UO2)2+ mode is not Raman active, whereas both the nu3 and nu1 (UO2)2+ modes are infrared active. U-O bond lengths in uranyls were calculated from the spectra obtained and compared with bond lengths derived from crystal structure analyses. From the higher number of bands related to the uranyl and carbonate vibrations, the presence of symmetrically distinct (UO2)2+ and (CO3)2- units in both structures is proposed.
- Raman and infrared spectroscopies were used to characterise two samples of triclinic cejkaite Na4[UO2(CO3)3] and its synthetic trigonal analogue. The nu3 (UO2)2+ mode is not Raman active, whereas both the nu3 and nu1 (UO2)2+ modes are infrared active. U-O bond lengths in uranyls were calculated from the spectra obtained and compared with bond lengths derived from crystal structure analyses. From the higher number of bands related to the uranyl and carbonate vibrations, the presence of symmetrically distinct (UO2)2+ and (CO3)2- units in both structures is proposed. (en)
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Title
| - Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3]
- Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] (en)
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skos:prefLabel
| - Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3]
- Raman spectroscopic study of the uranyl carbonate mineral cejkaite and its comparison with synthetic trigonal Na4[UO2(CO3)3] (en)
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skos:notation
| - RIV/00023272:_____/10:#0001275!RIV11-MK0-00023272
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/00023272:_____/10:#0001275
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - cejkaite; uranyl; carbonate; Raman spectra; Infrared spectra (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Raman Spectroscopy
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Bahfenne, Silmarilly
- Frost, Ray Leslie
- Palmer, Sara J.
- Plášil, Jakub
- Sejkora, Jiří
- Čejka, Jiří
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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