About: Raman spectroscopic study of the uranyl carbonate mineral zellerite

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About: Raman spectroscopic study of the uranyl carbonate mineral zellerite Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Raman and infrared spectra of the uranyl mineral zellerite, Ca[(UO2)(CO3)2(H2O)2] 3H2O, were measured and tentatively interpreted. U-O bond in uranyl and O-H center dot center dot center dot O hydrogen bonds were calculated from the vibrational spectra. The presence of structurally nonequivalent water molecules in the crystal structure of zellerite was inferred. A proposed chemical formula of zellerite is supported. Raman bands at 3514, 3375 and 2945 cm-1 and broad infrared bands at 3513, 3396 and 3326 cm-1 are related to the v OH stretching vibrations of hydrogen-bonded water molecules. Observed wavenumbers of these vibrations prove that in fact hydrogen bonds participate in the crystal structure of zellerite. The presence of two bands at 1618 and 1681 cm-1 proves structurally distinct and nonequivalent water molecules in the crystal structure of zellerite. Raman and infrared spectra of the uranyl mineral zellerite, Ca[(UO2)(CO3)2(H2O)2] 3H2O, were measured and tentatively interpreted. U-O bond in uranyl and O-H center dot center dot center dot O hydrogen bonds were calculated from the vibrational spectra. The presence of structurally nonequivalent water molecules in the crystal structure of zellerite was inferred. A proposed chemical formula of zellerite is supported. Raman bands at 3514, 3375 and 2945 cm-1 and broad infrared bands at 3513, 3396 and 3326 cm-1 are related to the v OH stretching vibrations of hydrogen-bonded water molecules. Observed wavenumbers of these vibrations prove that in fact hydrogen bonds participate in the crystal structure of zellerite. The presence of two bands at 1618 and 1681 cm-1 proves structurally distinct and nonequivalent water molecules in the crystal structure of zellerite. (en)
Title	Raman spectroscopic study of the uranyl carbonate mineral zellerite Raman spectroscopic study of the uranyl carbonate mineral zellerite (en)
skos:prefLabel	Raman spectroscopic study of the uranyl carbonate mineral zellerite Raman spectroscopic study of the uranyl carbonate mineral zellerite (en)
skos:notation	RIV/00023272:_____/08:#0000997!RIV10-MK0-00023272
http://linked.open...avai/riv/aktivita	V
http://linked.open...avai/riv/aktivity	V
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Čejka, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Národní muzeum
http://linked.open...dnocenehoVysledku	391438
http://linked.open...ai/riv/idVysledku	RIV/00023272:_____/08:#0000997
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	zellerite; uranyl minerals; carbonates; Raman spectroscopy; infrared spectroscopy; mineralogy (en)
http://linked.open.../riv/klicoveSlovo	Raman spectroscopy infrared spectroscopy uranyl minerals carbonates mineralogy zellerite
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[BF6E7A18BCD3]
http://linked.open...i/riv/nazevZdroje	Journal of Raman Spectroscopy
http://linked.open...in/vavai/riv/obor	DB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	39
http://linked.open...iv/tvurceVysledku	Frost, Ray Leslie Čejka, Jiří Dickfos, Marilla J.
http://linked.open...ain/vavai/riv/wos	000256167200005
issn	0377-0486
number of pages	5 (xsd:int)

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