About: Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O

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About: Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The mineral marthozite, a uranyl selenite, has been characterised by Raman spectroscopy at 298 K. The bands at 812 and 797 cm-1 were assigned to the symmetric stretching modes of the (UO2)2+ and (SeO3)2 units, respectively. These values gave the calculated U-O bond lengths in uranyl of 1.799 and/or 1.814 angstrom. Average U-O bond length in uranyl is 1.795 angstrom, inferred from the X-ray single crystal structure analysis of marthozite by Cooper and Hawthorne. The broad band at 869 cm-1 was assigned to the v(3) antisymmetric stretching mode of the (UO2)2+ (calculated U-O bond length 1.808 angstrom). The band at 739 cm-1 was attributed to the v(3) antisymmetric stretching vibration of the (SeO3)2- units. The v(4) and the v(2) vibrational modes of the (SeO3)2- units were observed at 424 and 473 cm-1. The mineral marthozite, a uranyl selenite, has been characterised by Raman spectroscopy at 298 K. The bands at 812 and 797 cm-1 were assigned to the symmetric stretching modes of the (UO2)2+ and (SeO3)2 units, respectively. These values gave the calculated U-O bond lengths in uranyl of 1.799 and/or 1.814 angstrom. Average U-O bond length in uranyl is 1.795 angstrom, inferred from the X-ray single crystal structure analysis of marthozite by Cooper and Hawthorne. The broad band at 869 cm-1 was assigned to the v(3) antisymmetric stretching mode of the (UO2)2+ (calculated U-O bond length 1.808 angstrom). The band at 739 cm-1 was attributed to the v(3) antisymmetric stretching vibration of the (SeO3)2- units. The v(4) and the v(2) vibrational modes of the (SeO3)2- units were observed at 424 and 473 cm-1. (en)
Title	Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O (en)
skos:prefLabel	Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O Raman spectroscopic study of the uranyl selenite mineral marthozite Cu[(UO2)3(SeO3)2O2].8H2O (en)
skos:notation	RIV/00023272:_____/08:#0000996!RIV10-MK0-00023272
http://linked.open...avai/riv/aktivita	V
http://linked.open...avai/riv/aktivity	V
http://linked.open...iv/cisloPeriodika	10
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Čejka, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Národní muzeum
http://linked.open...dnocenehoVysledku	391441
http://linked.open...ai/riv/idVysledku	RIV/00023272:_____/08:#0000996
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	marthozite; uranyl minerals; selenites; Raman spectroscopy; mineralogy (en)
http://linked.open.../riv/klicoveSlovo	Raman spectroscopy uranyl minerals mineralogy marthozite selenites
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[10AD1CA53584]
http://linked.open...i/riv/nazevZdroje	Journal of Raman Spectroscopy
http://linked.open...in/vavai/riv/obor	DB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	39
http://linked.open...iv/tvurceVysledku	Frost, Ray Leslie Keeffe, Eloise C. Čejka, Jiří Dickfos, Marilla J.
http://linked.open...ain/vavai/riv/wos	000260355900014
issn	0377-0486
number of pages	6 (xsd:int)

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