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Description
| - The thermodynamics of the monomer-dimer equilibrium of five cationic monomethine cyanine dyes has been studied by means of UV-vis spectroscopy and advanced chemometrics methods. The dimerization constants were determined by studying the dependence of their absorption spectra on temperature in the range 20-75A degrees C and were found to be: 1.91 x 10(3), 1.53 x 10(3), 6.81 x 10(3), 5.18 x 10(3), and 8.28 x 10(3) dm(3) mol(-1) for 1, 2, 3, 4, and 5 respectively. The absorption spectra of the monomer and dimer forms of the dyes were also determined, as well as the enthalpy and entropy of the dimerization.
- The thermodynamics of the monomer-dimer equilibrium of five cationic monomethine cyanine dyes has been studied by means of UV-vis spectroscopy and advanced chemometrics methods. The dimerization constants were determined by studying the dependence of their absorption spectra on temperature in the range 20-75A degrees C and were found to be: 1.91 x 10(3), 1.53 x 10(3), 6.81 x 10(3), 5.18 x 10(3), and 8.28 x 10(3) dm(3) mol(-1) for 1, 2, 3, 4, and 5 respectively. The absorption spectra of the monomer and dimer forms of the dyes were also determined, as well as the enthalpy and entropy of the dimerization. (en)
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Title
| - The dimerization study of some cationic monomethine cyanine dyes by chemometrics method
- The dimerization study of some cationic monomethine cyanine dyes by chemometrics method (en)
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skos:prefLabel
| - The dimerization study of some cationic monomethine cyanine dyes by chemometrics method
- The dimerization study of some cationic monomethine cyanine dyes by chemometrics method (en)
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skos:notation
| - RIV/86652036:_____/12:00389263!RIV13-AV0-86652036
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/86652036:_____/12:00389263
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - dimerization; chemometrics; UV-vis spectroscopy; monomethine cyanine dyes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Russian Journal of Physical Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Kubista, Mikael
- Ahmadi, S.
- Deligeorgiev, T. G.
- Vasilev, A.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1134/S0036024412130201
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