About: Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The Prussian blue analogues represent well-known and extensively studied group of coordination species which has many remarkable applications due to their ion-exchange, electron transfer or magnetic properties. Among them, Co-Fe Prussian blue analogues have been extensively studied due to the photoinduced magnetization. Surprisingly, their suitability as precursors for solid-state synthesis of magnetic nanoparticles is almost unexplored. In this paper, the mechanism of thermal decomposition of [Co(en)3][Fe(CN)6] ? 2H2O (1a) is elucidated, including the topotactic dehydration, valence and spins exchange mechanisms suggestion and the formation of a mixture of CoFe2O4-Co3O4 (3:1) as final products of thermal degradation. The Prussian blue analogues represent well-known and extensively studied group of coordination species which has many remarkable applications due to their ion-exchange, electron transfer or magnetic properties. Among them, Co-Fe Prussian blue analogues have been extensively studied due to the photoinduced magnetization. Surprisingly, their suitability as precursors for solid-state synthesis of magnetic nanoparticles is almost unexplored. In this paper, the mechanism of thermal decomposition of [Co(en)3][Fe(CN)6] ? 2H2O (1a) is elucidated, including the topotactic dehydration, valence and spins exchange mechanisms suggestion and the formation of a mixture of CoFe2O4-Co3O4 (3:1) as final products of thermal degradation. (en)
Title	Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation (en)
skos:prefLabel	Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation Thermal decomposition of [Co(en)3][Fe(CN)6]?2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation (en)
skos:notation	RIV/61989592:15310/13:33145841!RIV14-GA0-15310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(GAP207/11/0841)
http://linked.open...iv/cisloPeriodika	28
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Drahoš, Bohuslav Zbořil, Radek Trávníček, Zdeněk Matiková Mal'Arová, Miroslava
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	110890
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/13:33145841
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Hexacyanidoferrate, Crystal structure, Thermal behavior, Mössbauer spectroscopy, Topotactic dehydration, Nanocomposite particles, CoFe2O4 (en)
http://linked.open.../riv/klicoveSlovo	Thermal behavior Crystal structure Mössbauer spectroscopy CoFe2O4 Hexacyanidoferrate Nanocomposite particles Topotactic dehydration
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[7EF40123A86E]
http://linked.open...i/riv/nazevZdroje	Chemistry Central Journal
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Regional Centre of Advanced Technologies and Materials Functionalized Magnetic Carriers Based on Iron Oxide Nanoparticles with Bonded Biologically Active or Magnetically Interesting Compounds Research team development of the Regional Centre of Advanced Technologies and Materials
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	7
http://linked.open...iv/tvurceVysledku	Trávníček, Zdeněk Zbořil, Radek Drahoš, Bohuslav Matiková Mal'Arová, Miroslava Černák, Juraj
http://linked.open...ain/vavai/riv/wos	000318288000001
issn	1752-153X
number of pages	18 (xsd:int)
http://bibframe.org/vocab/doi	10.1186/1752-153X-7-28
http://localhost/t...ganizacniJednotka	15310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 112 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software