About: 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules     Goto   Sponge   NotDistinct   Permalink

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Description
  • Dioxan ferra bis(dikarbollid): Paramagnetická funkční molekula široce využitelná jako stavební blok k zavedení Fe(III) centra do organických sloučenin. (cs)
  • The synthesis of a new, paramagnetic closo-[(8-(-CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe](0) (3) is reported. This compound can serve as a versatile building block for construction of both anionic and zwitterionic derivatives, as exemplified by the synthesis of a series of compounds of general formula closo-[(8-X-(CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe], bearing organic end groups (X = NC5H5 (4), (C6H5)(3)P (5), OH (6), and 2-O(1-CH3O-C6H4) (7)) attached to the cluster by a diethyleneglycol spacer. Molecular structures of 3, 4, 5 and 7 were determined by single-crystal X-ray diffraction analysis and by the long-time neglected method of paramagnetic, high field NMR (H-1, C-13 and B-11) spectroscopy.
  • The synthesis of a new, paramagnetic closo-[(8-(-CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe](0) (3) is reported. This compound can serve as a versatile building block for construction of both anionic and zwitterionic derivatives, as exemplified by the synthesis of a series of compounds of general formula closo-[(8-X-(CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe], bearing organic end groups (X = NC5H5 (4), (C6H5)(3)P (5), OH (6), and 2-O(1-CH3O-C6H4) (7)) attached to the cluster by a diethyleneglycol spacer. Molecular structures of 3, 4, 5 and 7 were determined by single-crystal X-ray diffraction analysis and by the long-time neglected method of paramagnetic, high field NMR (H-1, C-13 and B-11) spectroscopy. (en)
Title
  • 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules
  • 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules (en)
  • Dioxan ferra bis(dikarbollid): Paramagnetická funkční molekula široce využitelná jako stavební blok k zavedení Fe(III) centra do organických sloučenin (cs)
skos:prefLabel
  • 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules
  • 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules (en)
  • Dioxan ferra bis(dikarbollid): Paramagnetická funkční molekula široce využitelná jako stavební blok k zavedení Fe(III) centra do organických sloučenin (cs)
skos:notation
  • RIV/61388980:_____/07:00096579!RIV08-MSM-61388980
http://linked.open.../vavai/riv/strany
  • 4801;4804
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA400310613), P(LC523), Z(AV0Z40320502), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 22
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 463395
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/07:00096579
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • carboranes; dicarbollides; x-ray diffraction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [A17B79FA8A01]
http://linked.open...i/riv/nazevZdroje
  • Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 692
http://linked.open...iv/tvurceVysledku
  • Císařová, I.
  • Grüner, Bohumír
  • Macháček, Jan
  • Plešek, Jaromír
  • Čáslavský, J.
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-328X
number of pages
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