About: 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules

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About: 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Dioxan ferra bis(dikarbollid): Paramagnetická funkční molekula široce využitelná jako stavební blok k zavedení Fe(III) centra do organických sloučenin. (cs) The synthesis of a new, paramagnetic closo-[(8-(-CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe](0) (3) is reported. This compound can serve as a versatile building block for construction of both anionic and zwitterionic derivatives, as exemplified by the synthesis of a series of compounds of general formula closo-[(8-X-(CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe], bearing organic end groups (X = NC5H5 (4), (C6H5)(3)P (5), OH (6), and 2-O(1-CH3O-C6H4) (7)) attached to the cluster by a diethyleneglycol spacer. Molecular structures of 3, 4, 5 and 7 were determined by single-crystal X-ray diffraction analysis and by the long-time neglected method of paramagnetic, high field NMR (H-1, C-13 and B-11) spectroscopy. The synthesis of a new, paramagnetic closo-[(8-(-CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe](0) (3) is reported. This compound can serve as a versatile building block for construction of both anionic and zwitterionic derivatives, as exemplified by the synthesis of a series of compounds of general formula closo-[(8-X-(CH2CH2O)(2)-1,2-C2B9H10)(1',2'-C2B9H11)-3,3'-Fe], bearing organic end groups (X = NC5H5 (4), (C6H5)(3)P (5), OH (6), and 2-O(1-CH3O-C6H4) (7)) attached to the cluster by a diethyleneglycol spacer. Molecular structures of 3, 4, 5 and 7 were determined by single-crystal X-ray diffraction analysis and by the long-time neglected method of paramagnetic, high field NMR (H-1, C-13 and B-11) spectroscopy. (en)
Title	8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules (en) Dioxan ferra bis(dikarbollid): Paramagnetická funkční molekula široce využitelná jako stavební blok k zavedení Fe(III) centra do organických sloučenin (cs)
skos:prefLabel	8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules 8-Dioxane ferra(III) bis(dicarbollide): A paramagnetic functional molecule as versatile building block for introduction of a Fe(III) centre into organic molecules (en) Dioxan ferra bis(dikarbollid): Paramagnetická funkční molekula široce využitelná jako stavební blok k zavedení Fe(III) centra do organických sloučenin (cs)
skos:notation	RIV/61388980:_____/07:00096579!RIV08-MSM-61388980
http://linked.open.../vavai/riv/strany	4801;4804
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA400310613), P(LC523), Z(AV0Z40320502), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	22
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Grüner, Bohumír Plešek, Jaromír Macháček, Jan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	463395
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/07:00096579
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	carboranes; dicarbollides; x-ray diffraction (en)
http://linked.open.../riv/klicoveSlovo	x-ray diffraction dicarbollides carboranes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[A17B79FA8A01]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Mass spectrometric and electrophoretic research of boron cluster compounds
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	692
http://linked.open...iv/tvurceVysledku	Císařová, I. Grüner, Bohumír Macháček, Jan Plešek, Jaromír Čáslavský, J.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0022-328X
number of pages	4 (xsd:int)

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