About: The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Electrochemical properties of polymer gel electrolytes based on polymethylmethacrylate (PMMA) were studied by cyclic voltammetry and impedance spectroscopy using new solid-state PMMA-Cd-Cd2+ reference electrode. The suitable potential window of the PC-PMMA system was estimated from -0.2 to + 1.5 V versus Cd-Cd2+. New polymer gels containing ferrocene-ferricinium (Fc-Fc(+)) couple and other transition metal complexes were prepared by the direct polymerisation of methylmethacrylate (MMA) monomer and the solution of metal complex and supporting electrolyte in anhydrous aprotic solvent-propylene carbonate (PC). The half-wave potentials and apparent diffusion coefficients of used complexes and their dependence on the composition of the system (liquid or gel) were estimated. The results show that the PC-PMMA gel electrolyte can be described as a system of embedded solvent in the polymer network of PMMA without present monomer. Electrochemical properties of polymer gel electrolytes based on polymethylmethacrylate (PMMA) were studied by cyclic voltammetry and impedance spectroscopy using new solid-state PMMA-Cd-Cd2+ reference electrode. The suitable potential window of the PC-PMMA system was estimated from -0.2 to + 1.5 V versus Cd-Cd2+. New polymer gels containing ferrocene-ferricinium (Fc-Fc(+)) couple and other transition metal complexes were prepared by the direct polymerisation of methylmethacrylate (MMA) monomer and the solution of metal complex and supporting electrolyte in anhydrous aprotic solvent-propylene carbonate (PC). The half-wave potentials and apparent diffusion coefficients of used complexes and their dependence on the composition of the system (liquid or gel) were estimated. The results show that the PC-PMMA gel electrolyte can be described as a system of embedded solvent in the polymer network of PMMA without present monomer. (en) Byla studována kinetika elektrochemických redoxních reakcí ferrocenu a komplexů kobaltu v prostředí polymerních gelových elektrolytů na bázi PMMA - propylenkarbonát. U komplexů byly v prostředí kapalného a gelového elektrolytu stanoveny difúzní koeficienty. (cs)
Title	The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes (en) Elektrochemické redoxní procesy v PMMA gelových elektrolytech – chování komplexů přechodných kovů (cs)
skos:prefLabel	The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes The electrochemical redox process in PMMA gel electrolytes-behaviour of transition metal complexes (en) Elektrochemické redoxní procesy v PMMA gelových elektrolytech – chování komplexů přechodných kovů (cs)
skos:notation	RIV/61388980:_____/05:00021014!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	4469;4476
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/02/0731), P(KJB4813302), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	22
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Vondrák, Jiří Reiter, Jakub
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	519933
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00021014
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	polymer electrolyte; ferrocene; diffusion coefficient (en)
http://linked.open.../riv/klicoveSlovo	diffusion coefficient ferrocene polymer electrolyte
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[FAAB9784F051]
http://linked.open...i/riv/nazevZdroje	Electrochimica acta
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Transport, solvatation and sorption of ions in gel polymer electrolytes Komposite electrode materials deposited on ion exchanging membranes
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	50
http://linked.open...iv/tvurceVysledku	Reiter, Jakub Vondrák, Jiří Mička, Z.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0013-4686
number of pages	8 (xsd:int)

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