About: 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds

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About: 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields. Tetraethyl fluoromethylenebisphosphonate in the presence of cesium carbonate in DMF undergoes efficient 1,4-addition to Michael acceptors having terminal double bond such as alpha,beta-unsaturated ketones, esters, sulfones, sulfoxides, and phosphonates to yield the corresponding adducts (alpha-alkyl-alfa-fluoromethylenebisphosphonates) in good to excellent yields. (en)
Title	1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds (en)
skos:prefLabel	1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds 1,4-Addition of tetraethyl fluoromethylenebisphosphonate to alpha, beta-unsaturated compounds (en)
skos:notation	RIV/61388963:_____/11:00360880!RIV12-AV0-61388963
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GP203/08/P310), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Beier, Petr Opekar, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	243935
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/11:00360880
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	1,4-addition; phosphonates; fluorine (en)
http://linked.open.../riv/klicoveSlovo	4-addition 1 phosphonates fluorine
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[6E9D4C309617]
http://linked.open...i/riv/nazevZdroje	Journal of Fluorine Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Nucleophilic introduction of fluorinated groups using organo-phosphorus compounds
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	132
http://linked.open...iv/tvurceVysledku	Beier, Petr Opekar, Stanislav
http://linked.open...ain/vavai/riv/wos	000291286000009
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství
issn	0022-1139
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jfluchem.2011.03.011

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