About: Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible Cu I /Cu II Transition in an Unrestrained Cu(N^S) 2 Coordination Arrangement. An Experimental and DFT Study.

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About: Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible Cu I /Cu II Transition in an Unrestrained Cu(N^S) 2 Coordination Arrangement. An Experimental and DFT Study. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The structure of [Cu(mmb) 2 ](BF 4 ) with 1-methyl-2-(methylthiomethyl)-1H-benzimidazole (mmb) as bidentale N,S-donor ligand has been determined and compared with that of the copper(II) species [Cu(mmb) 2 (.eta.1-ClO 4 ](ClO 4 ).DFT calculations on [Cu(N^S) 2 ] + , [Cu(N^S) 2 ] 2+ and [Cu(N^S) 2 (OClO 3 )] + with N^S=2-methylthiomethyl-1H-benzimidazole confirm the essential role of the metal sulfur bonds in responding to the reversible CuI/II electron transfer process. The structure of [Cu(mmb) 2 ](BF 4 ) with 1-methyl-2-(methylthiomethyl)-1H-benzimidazole (mmb) as bidentale N,S-donor ligand has been determined and compared with that of the copper(II) species [Cu(mmb) 2 (.eta.1-ClO 4 ](ClO 4 ).DFT calculations on [Cu(N^S) 2 ] + , [Cu(N^S) 2 ] 2+ and [Cu(N^S) 2 (OClO 3 )] + with N^S=2-methylthiomethyl-1H-benzimidazole confirm the essential role of the metal sulfur bonds in responding to the reversible CuI/II electron transfer process. (en)
Title	Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible Cu I /Cu II Transition in an Unrestrained Cu(N^S) 2 Coordination Arrangement. An Experimental and DFT Study. Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible Cu I /Cu II Transition in an Unrestrained Cu(N^S) 2 Coordination Arrangement. An Experimental and DFT Study. (en)
skos:prefLabel	Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible Cu I /Cu II Transition in an Unrestrained Cu(N^S) 2 Coordination Arrangement. An Experimental and DFT Study. Crucial Role of the Cu-S Bonding for Structural Changes Accompanying the Reversible Cu I /Cu II Transition in an Unrestrained Cu(N^S) 2 Coordination Arrangement. An Experimental and DFT Study. (en)
skos:notation	RIV/61388955:_____/00:54000173!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	4731;4734
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(OC D15.10), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	21
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Záliš, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	707753
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/00:54000173
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	N/A (en)
http://linked.open.../riv/klicoveSlovo	N/A
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[3DA8D59DEBDB]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20D15.10
http://linked.open...UplatneniVysledku	2000
http://linked.open...v/svazekPeriodika	39
http://linked.open...iv/tvurceVysledku	Kaim, W. Záliš, Stanislav Albrecht, M. Hübler, K.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0020-1669
number of pages	4 (xsd:int)

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