About: Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	This experiment tested the reactivity of the cationic surfactant Resamin AE [N-(2-hydroxyethyl)-N-(2-hydroxy-4-oxa(C14 divided by 22-alkyl))-N,N-dimethylammonium chloride] with organophosphonate soman. It was confirmed that soman is incorporated in the micelle of Resamin AE and that the hydroxyl group or Resamin AE supports the hydrolysis of this organophosphonate. A further increase in reactivity was achieved by the addition of hydrogen peroxide into the reaction mixture. In contrast, if the concentration of neutral salts was increased, a decrease in the velocity of the hydrolysis was obtained. The hydrolytic efficacy of Resamin AE was also compared with that of hexadecyldimethyl-(2-hydroxyethyl)-ammonium bromide. Resamin AE appeared to be a more efficacious hydrolytic agent than other similar compounds due to its advantageous chemical structure. This experiment tested the reactivity of the cationic surfactant Resamin AE [N-(2-hydroxyethyl)-N-(2-hydroxy-4-oxa(C14 divided by 22-alkyl))-N,N-dimethylammonium chloride] with organophosphonate soman. It was confirmed that soman is incorporated in the micelle of Resamin AE and that the hydroxyl group or Resamin AE supports the hydrolysis of this organophosphonate. A further increase in reactivity was achieved by the addition of hydrogen peroxide into the reaction mixture. In contrast, if the concentration of neutral salts was increased, a decrease in the velocity of the hydrolysis was obtained. The hydrolytic efficacy of Resamin AE was also compared with that of hexadecyldimethyl-(2-hydroxyethyl)-ammonium bromide. Resamin AE appeared to be a more efficacious hydrolytic agent than other similar compounds due to its advantageous chemical structure. (en)
Title	Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE (en)
skos:prefLabel	Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE (en)
skos:notation	RIV/60162694:G44__/10:00002387!RIV11-MO0-G44_____
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(OVUOFVZ200803)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Cabal, Jiří Kuča, Kamil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ministerstvo obrany / Univerzita obrany - Fakulta vojenského zdravotnictví Hradec Králové
http://linked.open...dnocenehoVysledku	266390
http://linked.open...ai/riv/idVysledku	RIV/60162694:G44__/10:00002387
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	cationic surfactants; micellar catalysis; soman; decontamination; Resamin AE (en)
http://linked.open.../riv/klicoveSlovo	soman cationic surfactants decontamination micellar catalysis Resamin AE
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[2967BDF33F24]
http://linked.open...i/riv/nazevZdroje	Journal of Applied Biomedicine - print
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Development of novel decontaminants and disinfectants of skin based on micellar compounds
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	8
http://linked.open...iv/tvurceVysledku	Cabal, Jiří Kuča, Kamil
http://linked.open...ain/vavai/riv/wos	000277970800007
issn	1214-021X
number of pages	8 (xsd:int)
http://localhost/t...ganizacniJednotka	G44

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